Sulfonic Acid Supported on Magnetic Methylene-Based Organosilica as an Efficient and Recyclable Nanocatalyst for Biodiesel Production via Esterification

被引：27
作者：
Shaker, Masoumeh [1 ]
Elhamifar, Dawood [1 ]
机构：
[1] Univ Yasuj, Dept Chem, Yasuj, Iran
来源：
FRONTIERS IN ENERGY RESEARCH | 2020年 / 8卷
基金：
美国国家科学基金会;
关键词：
magnetic nanocatalyst; biodiesel production; esterification; recoverable catalyst; solvent-free conditions; IRON-OXIDE NANOPARTICLES; PERIODIC MESOPOROUS ORGANOSILICA; GRAPHENE OXIDE; SOLID ACID; ONE-STEP; CATALYST; TRANSESTERIFICATION; MICROSPHERES; PERFORMANCE; ENRICHMENT;
D O I：
10.3389/fenrg.2020.00078
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
In this paper, a novel sulfonic acid containing magnetic methylene-based organosilica with core-shell structure (Fe3O4@OS-SO3H) is synthesized, characterized and its catalytic application is investigated for biodiesel production via esterification of carboxylic acids with alcohols. The Fe3O4@OS-SO3H was synthesized via co-condensation of tetraethyl orthosilicate (TEOS) and 1,2-bis(triethoxysilyl)methane (BTEM) around magnetite nanoparticles. The Fe3O4@OS-SO3H nanocatalyst was characterized by using FT-IR, PXRD, TGA, VSM, TEM and SEM techniques. The catalytic study showed that the Fe3O4@OS-SO3H nanocomposite can be used as an effective, powerful, selective and recyclable catalyst for the esterification of carboxylic acids with alcohols at 70 degrees C under solvent-free conditions. This nanocatalyst was recovered and reused several times without significant decrease in efficiency and stability.
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页数：11
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共 78 条
[21]   A core-shell SO4/Mg-Al-Fe3O4 catalyst for biodiesel production [J].
Gardy, Jabbar ;
Nourafkan, Ehsan ;
Osatiashtiani, Amin ;
Lee, Adam F. ;
Wilson, Karen ;
Hassanpour, Ali ;
Lai, Xiaojun .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2019, 259
[22]   Preparation and characterization of hexamethylenetetramine-functionalized magnetic nanoparticles and their application as novel catalyst for the synthesis of pyranopyrazole derivatives [J].
Ghorbani-Vaghei, Ramin ;
Izadkhah, Vida .
APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (02)
[23]   Butter as a Feedstock for Biodiesel Production [J].
Haas, Michael J. ;
Adawi, Nadia ;
Berry, William W. ;
Feldman, Elaine ;
Kasprzyk, Stephen ;
Ratigan, Brian ;
Scott, Karen ;
Landsburg, Emily Bockian .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2010, 58 (13) :7680-7684
[24]   Cell Uptake and in Vitro Toxicity of Magnetic Nanoparticles Suitable for Drug Delivery [J].
Hafelli, Urs O. ;
Riffle, Judy S. ;
Harris-Shekhawat, Linda ;
Carmichael-Baranauskas, Anita ;
Mark, Framin ;
Dailey, James P. ;
Bardenstein, David .
MOLECULAR PHARMACEUTICS, 2009, 6 (05) :1417-1428
[25]   Manganese porphyrin immobilized on magnetic MCM-41 nanoparticles as an efficient and reusable catalyst for alkene oxidations with sodium periodate [J].
Hajian, Robabeh ;
Ehsanikhah, Amin .
CHEMICAL PHYSICS LETTERS, 2018, 691 :146-154
[26]   Sulfonic acid-functionalized periodic mesoporous organosilica [J].
Hamoudi, S ;
Kaliaguine, S .
MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 59 (2-3) :195-204
[27]   Characterization of Crude Glycerol from Biodiesel Plants [J].
Hu, Shengjun ;
Luo, Xiaolan ;
Wan, Caixia ;
Li, Yebo .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2012, 60 (23) :5915-5921
[28]   Nano-magnetic catalyst KF/CaO-Fe3O4 for biodiesel production [J].
Hu, Shengyang ;
Guan, Yanping ;
Wang, Yun ;
Han, Heyou .
APPLIED ENERGY, 2011, 88 (08) :2685-2690
[29]   Mild acid functionalization of metal-organic framework and its catalytic effect on esterification of acetic acid with n-butanol [J].
Hu, Xijun ;
Ma, Kai ;
Sabbaghi, Aghil ;
Chen, Xuanming ;
Chatterjee, Amrita ;
Lam, Frank L. Y. .
MOLECULAR CATALYSIS, 2020, 482
[30]   Catalytic applications of magnetic nanoparticles functionalized using iridium N-heterocyclic carbene complexes [J].
Iglesias, Diego ;
Sabater, Sara ;
Azua, Arturo ;
Mata, Jose A. .
NEW JOURNAL OF CHEMISTRY, 2015, 39 (08) :6437-6444
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