Sulfonic Acid Supported on Magnetic Methylene-Based Organosilica as an Efficient and Recyclable Nanocatalyst for Biodiesel Production via Esterification

被引：27
作者：
Shaker, Masoumeh [1 ]
Elhamifar, Dawood [1 ]
机构：
[1] Univ Yasuj, Dept Chem, Yasuj, Iran
来源：
FRONTIERS IN ENERGY RESEARCH | 2020年 / 8卷
基金：
美国国家科学基金会;
关键词：
magnetic nanocatalyst; biodiesel production; esterification; recoverable catalyst; solvent-free conditions; IRON-OXIDE NANOPARTICLES; PERIODIC MESOPOROUS ORGANOSILICA; GRAPHENE OXIDE; SOLID ACID; ONE-STEP; CATALYST; TRANSESTERIFICATION; MICROSPHERES; PERFORMANCE; ENRICHMENT;
D O I：
10.3389/fenrg.2020.00078
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
In this paper, a novel sulfonic acid containing magnetic methylene-based organosilica with core-shell structure (Fe3O4@OS-SO3H) is synthesized, characterized and its catalytic application is investigated for biodiesel production via esterification of carboxylic acids with alcohols. The Fe3O4@OS-SO3H was synthesized via co-condensation of tetraethyl orthosilicate (TEOS) and 1,2-bis(triethoxysilyl)methane (BTEM) around magnetite nanoparticles. The Fe3O4@OS-SO3H nanocatalyst was characterized by using FT-IR, PXRD, TGA, VSM, TEM and SEM techniques. The catalytic study showed that the Fe3O4@OS-SO3H nanocomposite can be used as an effective, powerful, selective and recyclable catalyst for the esterification of carboxylic acids with alcohols at 70 degrees C under solvent-free conditions. This nanocatalyst was recovered and reused several times without significant decrease in efficiency and stability.
引用
收藏
页数：11
相关论文
共 78 条
[1]   Magnetic nanoporous MCM-41 supported ionic liquid/palladium complex: An efficient nanocatalyst with high recoverability [J].
Abaeezadeh, Somayeh ;
Elhamifar, Dawood ;
Norouzi, Meysam ;
Shaker, Masoumeh .
APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (06)
[2]   One-step synthesis of solid sulfonic acid catalyst and its application in the acetalization of glycerol: crystal structure of cis-5-hydroxy-2-phenyl-1,3-dioxane trimer [J].
Adam, Farook ;
Batagarawa, Muazu Samaila ;
Hello, Kasim Mohammed ;
Al-Juaid, Salih S. .
CHEMICAL PAPERS, 2012, 66 (11) :1048-1058
[3]   Modelling and optimisation of biodiesel production from Euphorbia lathyris using ASPEN Hysys [J].
Adeniyi, Adewale George ;
Ighalo, Joshua O. ;
Adeoye, Akorede Samson ;
Onifade, Damilola Victoria .
SN APPLIED SCIENCES, 2019, 1 (11)
[4]   Hierarchical assembly of magnetic L1o-ordered FePt nanoparticles in block copolymer thin films [J].
Aissou, Karim ;
Alnasser, Thomas ;
Pecastaings, Gilles ;
Goglio, Graziella ;
Toulemonde, Olivier ;
Mornet, Stephane ;
Fleury, Guillaume ;
Hadziioannou, Georges .
JOURNAL OF MATERIALS CHEMISTRY C, 2013, 1 (07) :1317-1321
[5]   Synergy of Miniemulsion and Solvothermal Conditions for the Low-Temperature Crystallization of Magnetic Nanostructured Transition-Metal Ferrites [J].
Antonello, Alice ;
Jakob, Gerhard ;
Dolcet, Paolo ;
Momper, Rebecca ;
Kokkinopoulou, Maria ;
Landfester, Katharina ;
Munoz-Espi, Rafael ;
Gross, Silvia .
CHEMISTRY OF MATERIALS, 2017, 29 (03) :985-997
[6]   Role of functionalization: strategies to explore potential nano-bio applications of magnetic nanoparticles [J].
Bohara, Raghvendra A. ;
Thorat, Nanasaheb D. ;
Pawar, Shivaji H. .
RSC ADVANCES, 2016, 6 (50) :43989-44012
[7]   Synthesis of Fe3O4@SiO2@PMMA Core-Shell-Shell Magnetic Microspheres for Highly Efficient Enrichment of Peptides and Proteins for MALDI-ToF MS Analysis [J].
Chen, Hemei ;
Deng, Chunhui ;
Zhang, Xiangmin .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (03) :607-611
[8]   Direct synthesis of mesoporous sulfated silica-zirconia catalysts with high catalytic activity for biodiesel via esterification [J].
Chen, Xiao-Rong ;
Ju, Yi-Hsu ;
Mou, Chung-Yuan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (50) :18731-18737
[9]   Graphene Oxide: An Efficient Acid Catalyst for the Construction of Esters from Acids and Alcohols [J].
Chen, Zhengwang ;
Wen, Yuelu ;
Fu, Yejuan ;
Chen, Hai ;
Ye, Min ;
Luo, Guotian .
SYNLETT, 2017, 28 (08) :981-985
[10]   Functionalized Fe3O4@ Silica Core-Shell Nanoparticles as Microalgae Harvester and Catalyst for Biodiesel Production [J].
Chiang, Ya-Dong ;
Dutta, Saikat ;
Chen, Ching-Tien ;
Huang, Yu-Tzu ;
Lin, Kuen-Song ;
Wu, Jeffrey C. S. ;
Suzuki, Norihiro ;
Yamauchi, Yusuke ;
Wu, Kevin C. -W. .
CHEMSUSCHEM, 2015, 8 (05) :789-794
12345678