Synthesis and physico-chemical characterization of bolaamphiphiles derived from alkenyl D-xylosides

被引：20

作者：

Deleu, Magali ^{[2
]}

Damez, Celine ^{[1
]}

Gatard, Sylvain ^{[1
]}

Nott, Katherine ^{[2
]}

Paquot, Michel ^{[2
]}

Bouquillon, Sandrine ^{[1
]}

机构：

[1] Univ Reims, CNRS, Unite Mixte Rech React Select & Applicat, F-51687 Reims, France

[2] Univ Liege, Unite Chim Biol Ind, B-5030 Gembloux, Belgium

来源：

NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 10期

关键词：

SUGAR BOLA-AMPHIPHILES; BIPOLAR LIPID ANALOGS; AGGREGATION BEHAVIOR; UNSYMMETRICAL BOLAAMPHIPHILES; BUTADIENE TELOMERIZATION; MOLECULAR AGGREGATION; TITRATION CALORIMETRY; OLEFIN METATHESIS; BACILLUS-SUBTILIS; AQUEOUS-SOLUTIONS;

D O I：

10.1039/c1nj20158a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The two step synthesis of a new series of bolaamphiphiles derived from alkenyl D-xylosides is described. Yields between 57 and 90% have been reached. Aggregation behavior and membrane interaction properties of a particular sugar-bolaform composed of two xylose heads connected by an ether link to a hydrophobic chain comprising 18 carbon atoms and an insaturation were studied. Its CAC value (similar to 0.05 mM) is low compared to those of conventional surfactants. Thermodynamic analysis has revealed that the aggregation phenomenon is mainly driven by an entropy process. The compound is able to interact with DPPC monolayers, in particular if their surface pressure is >= 15 mN m(-1). Our results highlight the potential of this bolaamphiphile as surfactant and membrane interacting agent.

引用

页码：2258 / 2266

页数：9

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