Synthesis of Noria-like Macrocycles Containing Alkoxy Groups based on a Dynamic Covalent Chemistry (DCC) System by the A2+B4 Condensation

被引：14

作者：

Niina, Nobumitsu ^{[2
]}

Kudo, Hiroto ^{[1
]}

Nishikubo, Tadatomi ^{[1
]}

机构：

[1] Kanagawa Univ, Fac Engn, Dept Mat & Life Chem, Kanagawa Ku, Yokohama, Kanagawa 2218686, Japan

[2] Kanagawa Univ, Grad Sch Engn, Dept Appl Chem, Kanagawa Ku, Yokohama, Kanagawa 2218686, Japan

来源：

CHEMISTRY LETTERS | 2009年 / 38卷 / 12期

关键词：

COMBINATORIAL LIBRARIES; WATER;

D O I：

10.1246/cl.2009.1198

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We succeeded in the synthesis of new noria-like macrocycles by condensation of 3-alkoxyphenol as A(2) type monomers, and pentanedial as B-4 type monomer. These condensation reactions were performed using several acids as catalysts in ethanol and CHCl3. It was found that these reactions proceeded by DCC to afford soluble polymers, oligomers, and noria-like ladder macrocycles. As the result, the selective synthesis of the targeted noria-like macrocycles was achieved successfully in high yields.

引用

页码：1198 / 1199

页数：2

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