Pentacarbonyl(trimethylamine) chromium and Pentacarbonyl(trimethylamine) Molybdenum

被引：4
|
作者：
Findlater, Michael [1 ]
Hill, Nicholas J. [1 ]
Cowley, Alan H. [1 ]
机构：
[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 01期
基金：
美国国家科学基金会;
关键词：
Crystal structure; Chromium; Molybdenum; Trimethylamine; Carbonyl; CRYSTAL-STRUCTURE; COMPLEXES; PYRIDINE; TUNGSTEN;
D O I：
10.1007/s10870-009-9626-9
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Pentacarbonyl(trimethylamine) chromium (1) and pentacarbonyl(trimethylamine) molybdenum (2) are isomorphous and crystallize in the space group P(2)1/n, a = 6.8267(14) angstrom, b = 11.269(2) angstrom, c = 14.692(3) angstrom, beta = 102.89(3)degrees, V = 1,101.8(4) angstrom(3), Z = 4 for 1 and a = 6.949(5) angstrom, b = 11.362(5) angstrom, c = 14.927(5) angstrom, b = 102. 639(5)degrees, V = 1,150.0(10) angstrom(3), Z = 4 for 2; both compounds possess distorted octahedral molecular geometries that result from the steric influence of the coordinated amine ligand.
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页码：64 / 66
页数：3
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