Solid acid catalyzed synthesis of furans from carbohydrates

被引:102
作者
Bhaumik, Prasenjit [1 ]
Dhepe, Paresh Laxmikant [1 ]
机构
[1] CSIR, Natl Chem Lab, Catalysis & Inorgan Chem Div, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India
来源
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING | 2016年 / 58卷 / 01期
关键词
solid acid catalyst; Biomass conversion; hemicelluloses; furfural; carbohydrates; furans; cellulose; HMF; LIQUID-PHASE DEHYDRATION; ONE-POT SYNTHESIS; EFFICIENT HETEROGENEOUS CATALYST; HOT COMPRESSED WATER; ION-EXCHANGE-RESIN; D-XYLOSE; FRUCTOSE DEHYDRATION; BIOMASS CONVERSION; HEMICELLULOSE HYDROLYSIS; SELECTIVE CONVERSION;
D O I
10.1080/01614940.2015.1099894
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The alternative feedstock, biomass (particularly lignocelluloses), having the profuse availability, is promising for the synthesis of several value-added chemicals which are currently obtained from fossil feedstock. In this article, the synthesis of two extremely significant furan chemicals viz. furfural and 5-hydroxymethylfurfural (HMF) are discussed. In the synthesis of furans from biomass, numerous challenges, i.e., use of edible sugars as substrates, selectivity to furans, their isolation in pure form, reuse of catalyst, environmental issues, etc., are perceived and in the recent past researchers tried to resolve those by developing advance methodologies. This article comprehensively summarizes the latest progress made in the above-mentioned areas and also provides commentary on the analyses of results, rationale for observed activity and mechanisms, etc. It also discusses future aspects of this work.
引用
收藏
页码:36 / 112
页数:77
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