Symmetry as a Tool for Solving Chemical Problems

被引：6

作者：

Moberg, Christina ^{[1
]}

机构：

[1] KTH Royal Inst Technol, Organ Chem, Dept Chem, SE-10044 Stockholm, Sweden

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2021年 / 94卷 / 02期

关键词：

Chirality; Selectivity; Symmetry; DEWAR BENZENE; KINETIC RESOLUTION; C-3; SYMMETRY; REARRANGEMENT; RECOGNITION; DERIVATIVES; LIGAND; ACID;

D O I：

10.1246/bcsj.20200338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Symmetry is found all around us. It is a fundamental concept in the arts as well as in the sciences. In chemical reactions, the use of reagents and catalysts with rotational symmetry decreases the number of transition states, a situation that may lead to increased selectivity. The presence of symmetry facilitates strucure determinations, and symmetry arguments may be helpful for elucidating mechanisms and for gaining insight into dynamic molecular processes.

引用

页码：558 / 564

页数：7

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