Microwave-Assisted One-Pot Synthesis of Hyperbranched Epoxide-Amine Adducts

被引：7
|
作者：
Theis, Julia [1 ]
Ritter, Helmut [1 ]
Klee, Joachim E. [2 ]
机构：
[1] Univ Dusseldorf, Inst Organ Chem & Macromol Chem, D-40225 Dusseldorf, Germany
[2] Dentsply DeTrey Forsch & Entwicklung, D-78467 Constance, Germany
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2009年 / 30卷 / 16期
关键词：
addition polymerization; epoxide-amine adducts; hyperbranched; microwave; transfer hydrogenation; TRANSFER HYDROGENATION; POLYMER SYNTHESIS; IRRADIATION; ALKENES; FORMATE; WATER;
D O I：
10.1002/marc.200900157
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Hyperbranched epoxide-amine adducts were synthesized by a one-pot microwave (MW) assisted reaction. 4-(2,3-epoxypropyl-1-oxy)benzonitrile was hydrogenated using Pd/C under microwave conditions, forming the AB(2) monomer 1-aminomethyl-4-(2,3-epoxypropyl-1-oxy)benzene. Depending on the reaction temperature this monomer immediately reacts to give hyperbranched epoxide-amine adducts. Mass spectrometric investigations proved the formation of a homologous series of oligomers containing up to six repeating units. Due to the complexing properties of the poly(amino alcohol) moieties in the presence of Cu2+ ions, large aggregates were formed.
引用
收藏
页码：1424 / 1427
页数：4
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