Luminescent zinc and cadmium metal-organic frameworks based on tetrazole ligands

被引:34
|
作者
Hu, Tuoping [1 ,2 ]
Liu, Longjie [1 ]
Lv, Xiaoli [1 ]
Chen, Xiaohui [1 ]
He, Haiyan [1 ]
Dai, Fangna [1 ]
Zhang, Guoqing [1 ]
Sun, Daofeng [1 ]
机构
[1] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China
[2] N Univ China, Dept Chem, Taiyuan 030051, Shanxi, Peoples R China
关键词
Tetrazole; Metal-organic framework; Fluorescence; COORDINATION POLYMERS; 5-SUBSTITUTED; 1H-TETRAZOLES; BIS(IMIDAZOLE) LIGANDS; HYDROGEN STORAGE; NETWORK; DIVERSITY; NITRILES; CHANNELS; CHAINS;
D O I
10.1016/j.poly.2009.05.015
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Three metal-organic frameworks with 1D zigzag chain [Zn(dte)(H2O)(3)]center dot 2H(2)O (1). 2D double layer [Cd(dtb)(H2O)(phen)] (2), 3D network [Zn(dte)(phen)] (3) based on tetrazole-based ligands (H(2)dtb = 1,3-dis(2H-tetrazol-5-yl)benzene, H(2)dte = 1,4-ditetrazolylethylene, phen=1,10-phenanthroline), have been synthesized and characterized. All the compounds exhibit unusual strong luminescence at room temperature in the solid state and can be potentially used as luminescent materials. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:296 / 302
页数:7
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