Synthesis and characterization of poly[3-(6-tetrahydropyran-2-yloxyhexyl)-2,5-thienylene]

被引：10

作者：

Bolognesi, A ^{[1
]}

Mendichi, R ^{[1
]}

Schieroni, A ^{[1
]}

Villa, D ^{[1
]}

Ahumada, O ^{[1
]}

机构：

[1] ETH ZURICH,INST POLYMERE,CH-8092 ZURICH,SWITZERLAND

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1997年 / 198卷 / 10期

关键词：

D O I：

10.1002/macp.1997.021981024

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of poly[3-(6-tetrahydropyran-2-yloxyhexyl)-2,3-thienylene] has been performed with a nickel catalyst, obtaining a highly regioregular polymer. The deprotection of the pyranyl function restores the -OH group giving a polymer which is not soluble in the usual organic solvents but soluble in 1-methyl-2-pyrrolidone, indicating that no crosslinks are present. The protected form was characterised by means of GPC, H-1 NMR, FTIR and UV-Vis spectroscopy and was found to give Langmuir-Blodgett multilayered structures.

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页码：3277 / 3284

页数：8

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