Reactions of arenediazonium tetrafluoroborates with 1,4-bis(acryloyloxy)butane in the presence of thiocyanate ion

被引：0

作者：

Gorbovoi, PM ^{[1
]}

Baranovskii, VS

Koval'skii, YP

Grishchuk, BD

机构：

[1] Gnatyuk Ternopol State Pedag Univ, Ternopol, Ukraine

[2] Lvovskaya Politekh Natl Univ, Lvov, Ukraine

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 08期

关键词：

Copper; Acetone; Butane; Thiocyanate; Tetrafluoroborates;

D O I：

10.1023/A:1020823611959

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first thiocyanatoarylation reaction with an unsaturated compound containing two isolated multiple bonds, 1,4-bis(acryloyloxy)butane, was effected. The reactions of 1,4-bis(acryloyloxy)butane with arenediazonium tetrafluoroborates occur in aqueous acetone (1 :2) in the presence of copper tetrafluoroborate and thiocyanate ion and involve only one multiple bond to give 1-acryloyloxy-4-(2-thiocyanato-3-arylpropionyloxy)butanes. Irrespective of reactant ratio, the second multiple bond undergoes no thiocyanatoarylation.

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收藏

页码：1230 / 1232

页数：3

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