Reactions of arenediazonium tetrafluoroborates with 1,4-bis(acryloyloxy)butane in the presence of thiocyanate ion

被引：0

作者：

Gorbovoi, PM ^{[1
]}

Baranovskii, VS

Koval'skii, YP

Grishchuk, BD

机构：

[1] Gnatyuk Ternopol State Pedag Univ, Ternopol, Ukraine

[2] Lvovskaya Politekh Natl Univ, Lvov, Ukraine

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 08期

关键词：

Copper; Acetone; Butane; Thiocyanate; Tetrafluoroborates;

D O I：

10.1023/A:1020823611959

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first thiocyanatoarylation reaction with an unsaturated compound containing two isolated multiple bonds, 1,4-bis(acryloyloxy)butane, was effected. The reactions of 1,4-bis(acryloyloxy)butane with arenediazonium tetrafluoroborates occur in aqueous acetone (1 :2) in the presence of copper tetrafluoroborate and thiocyanate ion and involve only one multiple bond to give 1-acryloyloxy-4-(2-thiocyanato-3-arylpropionyloxy)butanes. Irrespective of reactant ratio, the second multiple bond undergoes no thiocyanatoarylation.

引用

页码：1230 / 1232

页数：3

共 24 条

[1] Reactions of Arenediazonium Tetrafluoroborates with 1,4-Bis(acryloyloxy)butane in the Presence of Thiocyanate Ion
P. M. Gorbovoi
V. S. Baranovskii
Ya. P. Koval'skii
B. D. Grishchuk
Russian Journal of General Chemistry, 2002, 72 : 1230 - 1232
[2] Reactions of arenediazonium tetrafluoroborates with 3-chloro-2-methylpropene in the presence of potassium chloride, bromide, and thiocyanate
Gorbovoi, P. M.
Tulaidan, G. N.
Grishchuk, B. D.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2008, 78 (01) : 133 - 135
[3] Reactions of arenediazonium tetrafluoroborates with 3-chloro-2-methylpropene in the presence of potassium chloride, bromide, and thiocyanate
P. M. Gorbovoi
G. N. Tulaidan
B. D. Grishchuk
Russian Journal of General Chemistry, 2008, 78 : 133 - 135
[4] Molecular and crystal structures of bis{1,4-bis(1,2,4-triazol-1-yl)butane}dichlorocobalt(II)
L. Shen
Russian Journal of Coordination Chemistry, 2009, 35 : 772 - 775
[5] Molecular and crystal structure of bis{1,4-bis(1,2,4-triazol-1-yl)butane}dibromocadmium(II)
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Russian Journal of Coordination Chemistry, 2010, 36 : 117 - 119
[6] Synthesis, characterization, and spectroscopic studies of novel transition metal complexes with N,N′-bis(salicylaldehydene)-1,4-bis(4-chloro-2-aminophenoxy)butane
H. Temel
S. İlhan
Russian Journal of Coordination Chemistry, 2007, 33 : 918 - 921
[7] Improved synthesis, structure, and reactivity of 1,4-bis(trimethylsilyl)octafluorobutane
Chen, Bo
Vicic, David A.
JOURNAL OF FLUORINE CHEMISTRY, 2014, 167 : 139 - 142
[8] Reaction of arenediazonium tetrafluoroborates with 3-(allyloxy)propane-1,2-diol and 2,2-bis(allyloxymethyl)butan-1-ol in the presence of thiocyanates
Grishchuk, BD
Baranovskii, VS
Koval'skii, YP
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RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2004, 74 (12) : 1907 - 1910
[9] Reaction of arenediazonium tetrafluoroborates with 3-(allyloxy)propane-1,2-diol and 2,2-bis(allyloxymethyl)butan-1-ol in the presence of thiocyanates
B. D. Grishchuk
V. S. Baranovskii
Ya. P. Koval’skii
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Russian Journal of General Chemistry, 2004, 74 : 1907 - 1910
[10] Synthesis and spectral characterization of macrocyclic NiII complexes derived from various diamines, NiII perchlorate and 1,4-bis(2-carboxyaldehydephenoxy)butane
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Transition Metal Chemistry, 2007, 32 : 1012 - 1017

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