Rare earth ion controlled crystallization of mica glass-ceramics

被引:27
作者
Garai, Mrinmoy [1 ]
Karmakar, Basudeb [1 ]
机构
[1] Cent Glass & Ceram Res Inst, CSIR, Glass Div, Glass Sci & Technol Sect, 196 Raja SC Mullick Rd, Kolkata 700032, India
关键词
Glass; Crystallization; Glass-ceramics; Microstructure; Thermal expansion; Microhardness; UP-CONVERSION LUMINESCENCE; FLUOROPHLOGOPITE MICA; MICROSTRUCTURE; CE;
D O I
10.1016/j.jallcom.2016.03.296
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In understanding the effects of rare earth ions to control the crystallization and microstructure of alkaline boroaluminosilicate system, the CeO2, Nd2O3, Sm2O3 and Gd2O3 doped K2O-MgO-B2O3-Al2O3-SiO2-F glasses were synthesized by melt-quenching at 1550 degrees C. Higher density (2.82-3.06 g cm(-3)) and thermal stability (glass phase) is experiential on addition of rare earth content, which also affects in increasing the glass transition temperature (Tg) and crystallization temperature (Tc). Decrease of thermal expansion in glasses with rare earth ion content is maintained by the stabilization of glass matrix owing to their large cationic field strength. A significant change in the non-isothermal DSC thermogram observed at 750-1050 degrees C is attributed to fluorophlogopite crystallization. Opaque glass-ceramics were prepared from such glasses by single step heat-treatment at 1050 degrees C; and the predominant crystalline phases are identified as fluorophlogopite mica, KMg3(AlSi3O10) F2 by XRD and EDX analysis. The compact glassceramic microstructure by the agglomeration of fluorophlogopite mica crystallites (crystal size similar to 100 e500 nm, FESEM) is achieved in attendance of rare earth ion; and such microstructure controlled the variation of density, thermal expansion and microhardness value. Higher thermal expansion (11.11 e14.08 - 10(-6)/K at 50-800 degrees C and 50-900 degrees C) of such glass-ceramics approve that these rare earth containing glasses can be useful for high temperature vacuum sealing application with metal or solid electrolyte. The increase of Vickers microhardness (5.27-5.61 GPa) in attendance of rare earth ions is attributed to the compact crystallinity of fluorophlogopite mica glass-ceramic microstructure. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:360 / 369
页数:10
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