Facile Construction of Bi2Sn2O7/g-C3N4 Heterojunction with Enhanced Photocatalytic Degradation of Norfloxacin

被引:20
作者
Zhu, Zhengru [1 ]
Xia, Haiwen [1 ]
Li, Hong [2 ]
Han, Songlin [1 ]
机构
[1] Liaoning Normal Univ, Sch Geog, Dalian 116029, Peoples R China
[2] Dalian Naval Acad, Dept Basic, Dalian 116018, Peoples R China
关键词
Bi2Sn2O7; g-C3N4; heterojunction; photocatalyst; norfloxacin; water pollution control; NANOCOMPOSITE; TETRACYCLINE; PERFORMANCE; G-C3N4; NANOPARTICLES; FABRICATION; NANOSHEETS; COMPOSITE;
D O I
10.3390/inorganics10090131
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
To mitigate antibiotic residues in the water environment, Bi2Sn2O7/g-C3N4 (BSCN) heterojunction was fabricated by a facile ultrasound-assisted hydrothermal method. The microstructure, morphology, and optical properties of Bi2Sn2O7/g-C3N4 heterojunction was studied by XRD, FTIR, XPS, SEM, TEM, UV-Vis DRS, and PL. The degradation rate of 20 mg/L norfloxacin (NOR) under visible light for 3 h was adopted as one of the indexes to evaluate the photocatalytic performance of Bi2Sn2O7/g-C3N4 heterojunction. Embellished with 20% Bi2Sn2O7 (BSO), the Bi2Sn2O7/g-C3N4 heterojunction decomposed 94% NOR in the experimental solution, which was 2.35 and 3.03 times as much as pristine g-C3N4 and bare Bi2Sn2O7, respectively. In addition, the Bi2Sn2O7/g-C3N4 heterojunction still eliminated 89% of NOR after five cycles, portending outstanding stability and cyclability of photocatalytic activity. A possible photocatalytic mechanism of Bi2Sn2O7/g-C3N4 heterojunction for NOR degradation is proposed.
引用
收藏
页数:13
相关论文
共 60 条
[1]   NGQD active sites as effective collectors of charge carriers for improving the photocatalytic performance of Z-scheme g-C3N4/Bi2WO6 heterojunctions [J].
Che, Huinan ;
Liu, Chunbo ;
Hu, Wei ;
Hu, Hao ;
Li, Jinqiao ;
Dou, Jianying ;
Shi, Weidong ;
Li, Chunmei ;
Dong, Hongjun .
CATALYSIS SCIENCE & TECHNOLOGY, 2018, 8 (02) :622-631
[2]   Facile fabrication of a direct Z-scheme Ag2CrO4/g-C3N4 photocatalyst with enhanced visible light photocatalytic activity [J].
Deng, Yaocheng ;
Tang, Lin ;
Zeng, Guangming ;
Wang, Jiajia ;
Zhou, Yaoyu ;
Wang, Jingjing ;
Tang, Jing ;
Liu, Yani ;
Peng, Bo ;
Chen, Fei .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 421 :209-221
[3]   Fabrication of Highly Efficient Bi2Sn2O7/C3N4 Composite with Enhanced Photocatalytic Activity for Degradation of Organic Pollutants [J].
Elhaddad, Engy ;
Rehman, Wajid ;
Waseem, Muhammad ;
Nawaz, Mohsan ;
Haq, Sirajul ;
Guo, Cun-Yue .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2021, 31 (01) :172-179
[4]   Enhanced photocatalytic activities of g-C3N4 with large specific surface area via a facile one-step synthesis process [J].
Feng, Deqiang ;
Cheng, Yahui ;
He, Jie ;
Zheng, Lingcheng ;
Shao, Dawei ;
Wang, Weichao ;
Wang, Weihua ;
Lu, Feng ;
Dong, Hong ;
Liu, Hui ;
Zheng, Rongkun ;
Liu, Hui .
CARBON, 2017, 125 :454-463
[5]   Facile synthesis of heterostructured YVO4/g-C3N4/Ag photocatalysts with enhanced visible-light photocatalytic performance [J].
Gao, Yu ;
Lin, Junying ;
Zhang, Qingzhe ;
Yu, He ;
Ding, Fu ;
Xu, Baotong ;
Sun, Yaguang ;
Xu, Zhenhe .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 224 :586-593
[6]   Effect and study of reducing agent NaBH4 on Bi/BiOBr/CdS photocatalyst [J].
Gao, Zhanyao ;
Yao, Binghua ;
Xu, Tiantian ;
Ma, Minmin .
MATERIALS LETTERS, 2020, 259
[7]   Photocatalytic properties of amine functionalized Bi2Sn2O7/rGO nanocomposites [J].
Gnanamoorthy, G. ;
Muthamizh, S. ;
Sureshbabu, K. ;
Munusamy, S. ;
Padmanaban, A. ;
Kaaviya, A. ;
Nagarajan, R. ;
Stephen, A. ;
Narayanan, V. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2018, 118 :21-31
[8]   Defective ultra-thin two-dimensional g-C3N4 photocatalyst for enhanced photocatalytic H2 evolution activity [J].
Han, Changcun ;
Su, Pengfei ;
Tan, Baohua ;
Ma, Xinguo ;
Lv, Hui ;
Huang, Chuyun ;
Wang, Pan ;
Tong, Zhengfu ;
Li, Gen ;
Huang, Yizhong ;
Liu, Zhifeng .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 581 :159-166
[9]   Facile solvothermal synthesis of a Z-Scheme 0D/3D CeO2/ZnIn2S4 heterojunction with enhanced photocatalytic performance under visible light irradiation [J].
Hao, Chen-chen ;
Tang, Yu-bin ;
Shi, Wei-long ;
Chen, Fang-yan ;
Guo, Feng .
CHEMICAL ENGINEERING JOURNAL, 2021, 409
[10]   Ultrasound assisted dispersion of Bi2Sn2O7-C3N4 nanophotocatalyst over various amount of zeolite Y for enhanced solar-light photocatalytic degradation of tetracycline in aqueous solution [J].
Heidari, Shirin ;
Haghighi, Mohammad ;
Shabani, Maryam .
ULTRASONICS SONOCHEMISTRY, 2018, 43 :61-72