Highly cross-linked, self-doped polyaniline exhibiting unprecedented hardness

被引：31

作者：

Deore, BA ^{[1
]}

Yu, IS ^{[1
]}

Aguiar, PM ^{[1
]}

Recksiedler, C ^{[1
]}

Kroeker, S ^{[1
]}

Freund, MS ^{[1
]}

机构：

[1] Univ Manitoba, Dept Chem, Winnipeg, MB R3T 2N2, Canada

来源：

CHEMISTRY OF MATERIALS | 2005年 / 17卷 / 15期

关键词：

D O I：

10.1021/cm0505392

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The use of a latest method for the generation of a cross-linked, self-doped conducting polymer is discussed. It was observed that no fillers or other nonconducting cross-linking agents are required that will ultimately reduce connectivity. The method was demonstrated by self-cross-linking poly(anilineboronic acid) (PABA), which results in the creation of four-coordinates boron through the formation of a dative boron-imine bond. In addition to a retaining a significant degree of conductivity, the cross-linked PABA exhibited unprecented hardness, surpassing more common hard polymers.

引用

页码：3803 / 3805

页数：3

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