Improved hydrogen production from formic acid on a Pd/C catalyst doped by potassium

被引：104

作者：

Bulushev, Dmitri A. ^{[1
,2
]}

Jia, Lijun ^{[1
,2
]}

Beloshapkin, Sergey ^{[2
]}

Ross, Julian R. H. ^{[1
]}

机构：

[1] Univ Limerick, Chem & Environm Sci Dept, Limerick, Ireland

[2] Univ Limerick, Mat & Surface Sci Inst, Limerick, Ireland

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 35期

基金：

爱尔兰科学基金会;

关键词：

DECOMPOSITION;

D O I：

10.1039/c2cc31027a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The rate of hydrogen production from vapour-phase formic acid decomposition can be increased by 1-2 orders of magnitude by doping a Pd/C catalyst with potassium ions. Surface potassium formate and/or bicarbonate species could be involved in the rate-determining step of this reaction.

引用

页码：4184 / 4186

页数：3

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