Synthesis of Two Lead Complexes of Propellant Stabilizer Compounds: In Pursuit of Novel Propellant Additives

被引：5

作者：

Lundell, Carl E. ^{[1
,2
]}

O'Sullivan, Owen T. ^{[1
]}

Gau, Michael R. ^{[1
]}

Zdilla, Michael J. ^{[1
]}

机构：

[1] Temple Univ, Dept Chem, 1901 N 13th St, Philadelphia, PA 19122 USA

[2] US Mil Acad, Dept Chem & Life Sci, West Point, NY 10996 USA

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 35期

关键词：

disruptive energetics; energetic materials; energy density; explosives; propellants; THERMAL-DECOMPOSITION; MODIFIERS;

D O I：

10.1002/slct.201701791

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two lead complexes, Tetrakis(mu(3)-(4-methyl-3-nitrophenyl imido lead (II))) 1, and Bis(2-nitrodiphenyl amido lead(II)) 2, were prepared by protolysis of bis(bis(trimethylsilyl)amido)lead(II) with two compounds relevant to double-base propellant stabilizers: 2-nitrodiphenylamine (NDPA) and 4-methyl-3-nitro-aniline. Crystal structures were determined as tetrahydrofuran solvates, and exhibit a number of unusual geometric features, including low lead coordination number. Heats of combustion and formation were determined using bomb calorimetry and converted to energy density using crystallographic densities. Compound 1 has an energy density of 30 MJ/L, whereas 2 was 38.2 MJ/L.

引用

页码：11673 / 11676

页数：4

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