Room-Temperature All-Solid-State Sodium Battery Based on Bulk Interfacial Superionic Conductor

被引：20

作者：

Hu, Chenji ^{[1
,2
,3
]}

Qi, Jizhen ^{[3
]}

Zhang, Yixiao ^{[1
,2
]}

Xie, Sijie ^{[3
]}

Liu, Baotong ^{[3
]}

Xue, Guoyong ^{[3
]}

Chen, Daiqian ^{[3
]}

Zheng, Qinfeng ^{[1
,2
]}

Li, Ping ^{[4
]}

Bo, Shou-hang ^{[4
]}

Shen, Yanbin ^{[3
]}

Chen, Liwei ^{[1
,2
,3
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Frontiers Sci Ctr Transformat Mol, Shanghai 200240, Peoples R China

[2] Shanghai Jiao Tong Univ, In Situ Ctr Phys Sci, Shanghai 200240, Peoples R China

[3] Chinese Acad Sci, CAS Ctr Excellence Nanosci, Suzhou Inst Nanotech & NanoBion SINANO, I Lab, Suzhou 215123, Peoples R China

[4] Shanghai Jiao Tong Univ, Univ Michigan Shanghai Jiao Tong Univ Joint Inst, Shanghai 200240, Peoples R China

来源：

NANO LETTERS | 2021年 / 21卷 / 24期

基金：

中国国家自然科学基金;

关键词：

Bulk interfacial superionic conductors; Interlayer; Sodium metal battery; All-solid-state battery; ION BATTERIES; POLYMER ELECTROLYTE; NA-ION; PROGRESS;

D O I：

10.1021/acs.nanolett.1c03605

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

All-solid-state sodium batteries (ASSSBs) are attractive alternatives to lithium-ion batteries for grid-scale energy storage due to their high safety and ubiquitous distribution of Na sources. A critical component for ASSSB is sodium-ion conducting solid-state electrolyte (SSE). Here, we report a high-performance sodium-ion SSE with the recently developed bulk interfacial superionic conductor (BISC) concept. The ionic conductivity and areal conductance of the Na+ BISC at 25 degrees C reaches 6.5 x 10(-4) S cm(-1) and 260 mS cm(-2), respectively. Using NaxCo0.7Mn0.3O2 (x approximate to 1.0, NaCMO) as the cathode active material, all-solid-state Na parallel to NaCMO batteries exhibiting small overpotential and similar to 180 cycle life are demonstrated under room temperature. This approach may also be used to prepare other metal ion, such as Mg2+, Al3+, and K+, based all-solid-state batteries.

引用

页码：10354 / 10360

页数：7

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