Chiral recognition in silver(I) olefin complexes with chiral diamines. Resolution of racemic alkenes and NMR discrimination of enantiomers

被引：17

作者：

Cucciolito, ME ^{[1
]}

Flores, G ^{[1
]}

Vitagliano, A ^{[1
]}

机构：

[1] Univ Naples Federico II, Complesso Univ Monte Sant Angelo, Dipartimento Chim, I-80126 Naples, Italy

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 01期

关键词：

D O I：

10.1021/om0341653

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The fragment [(chiral diamine)Ag](+) is a very useful reagent, both for the resolution of racemic alkenes and for the H-1 or C-13 NMR determination of the enantiomeric abundances of chiral olefinic compounds.

引用

页码：15 / 17

页数：3

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