Adiabatic dipolar recoupling in solid-state NMR: The DREAM scheme

被引:177
作者
Verel, R [1 ]
Ernst, M [1 ]
Meier, BH [1 ]
机构
[1] ETH Honggerberg, Chem Phys Lab, CH-8093 Zurich, Switzerland
关键词
D O I
10.1006/jmre.2001.2310
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A theoretical treatment of the DREAM adiabatic homonuclear recoupling experiment is given using Floquet theory. An effective Hamiltonian is derived analytically and the time evolution of the density operator in the adiabatic limit is described. Shape cycles are proposed and characterized experimentally. Application to spin-pair filtering and as a mixing period in a 2D correlation experiment is explored and the experimental results are compared to theoretical predictions and exact numerical simulations. (C) 2001 Academic Press.
引用
收藏
页码:81 / 99
页数:19
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