Synthesis, crystal structure and physical properties of charge transfer coordination complex, [Pt(H(2)DAG)(HDAG)][Ni(DMIT)(2)]center dot 1/2H(2)O center dot CH3CN center dot CH3OH

被引：2

作者：

Yamashita, M ^{[1
]}

Ichikawa, A ^{[1
]}

Hama, T ^{[1
]}

Ohishi, T ^{[1
]}

Manabe, T ^{[1
]}

Miyamae, H ^{[1
]}

Yoshida, D ^{[1
]}

Sugiura, S ^{[1
]}

Kitagawa, H ^{[1
]}

Iwasa, Y ^{[1
]}

Mitani, T ^{[1
]}

机构：

[1] JOSAI UNIV,DEPT CHEM,SAKADO,SAITAMA 35002,JAPAN

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1996年 / 284卷

关键词：

D O I：

10.1080/10587259608037941

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A low-dimensional charge transfer coordination complex, [Pt(H2dag)(Hdag)] [Ni(dmit)2].1/2H2O.CH3CN.CH3OH (H2dag=diamino-glyoxime; dmit-1,3-dithiol-2-thione- 4,5-dithiolate) has been synthesized. In the crystal, [Pt(H2dag)(Hdag)] molecules and [Ni(dmit)2] molecules are dimerized, respectively, and the dimerized molecules are stacked alternatively, forming a linear chain structure. The intermolecular S...S contacts between [Ni(dmit)2] molecules in the neighboring linear chains are observed, and moreover intermolecular hydrogen-bonds between S of dmit and H of dag ligands in the neighboring linear chains are also observed, resulting in the two-dimensional network. Single-crystal electrical conductivity, absorption spectrum and magnetic susceptibility have been measured and their results are discussed.

引用

页码：391 / 398

页数：8

共 10 条

[1] MOLECULAR-METALS AND SUPERCONDUCTORS DERIVED FROM METAL-COMPLEXES OF 1,3-DITHIOL-2-THIONE-4,5-DITHIOLATE (DMIT) [J].