Sulfur-based hyper cross-linked polymers

被引：7

作者：

Monnereau, Laure ^{[1
]}

Grandclaudon, Charlotte ^{[1
]}

Muller, Thierry ^{[2
]}

Braese, Stefan ^{[1
,3
]}

机构：

[1] KIT, Inst Organ Chem, D-76131 Karlsruhe, Germany

[2] Clariant Prod Deutsch GmbH, Clariant Innovat Ctr, Grp Technol & Innovat, Grp Chem Res,Competence Ctr Colorants & Funct Che, D-65296 Frankfurt, Germany

[3] Inst Toxicol & Genet, D-76344 Eggenstein Leopoldshafen, Germany

来源：

RSC ADVANCES | 2015年 / 5卷 / 30期

关键词：

INTRINSIC MICROPOROSITY PIMS; TRIAZINE-BASED FRAMEWORKS; SURFACE-AREA; ORGANIC FRAMEWORKS; HYDROGEN STORAGE; MOLECULAR-SIEVE; COVALENT; NETWORKS; POLYMERIZATION; POROSITY;

D O I：

10.1039/c5ra01463h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various hyper cross-linked polymers (HCPs) based on tetrakis(thiylphenyl)methane were generated by sulphur-relevant chemistry. Disulfide and thioether connections were exploited as a direct route to produce three-dimensional polymers. HCPs based on a thio-ether connection were quantitatively generated in the presence of triethylamine and di-iodo derivatives by a nucleophilic substitution reaction. They exhibited a Brunauer-Emmett-Teller surface area of 177 m(2) g(-1) for N-2 adsorption at 77 K while disulfide HCPs directly generated by oxidation of the corresponding polythiophenol monomers did not exhibit any ability to store gaseous molecules. Thia-Michael addition between tetrakis(thiylphenyl) methane and N-aryl-bismaleimide derivatives was next realized and led to porous HCPs presenting a specific surface area up to 1675 m(2) g(-1) in sorption measurements using nitrogen gas at 77 K. These organic frameworks were insoluble in common organic solvents and showed a high thermal stability up to 500 degrees C.

引用

页码：23152 / 23159

页数：8

共 63 条

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