Chemical Reactivity of the Imidazole: A Semblance of Pyridine and Pyrrole?

被引：40

作者：

Richaud, Arlette ^{[1
]}

Barba-Behrens, Norah ^{[2
]}

Mendez, Francisco ^{[1
]}

机构：

[1] Univ Autonoma Metropolitana Iztapalapa, Div Ciencias Basicas & Ingn, Dept Quim, Mexico City 09340, DF, Mexico

[2] Univ Nacl Autonoma Mexico, Fac Quim, Dept Quim Inorgan, Mexico City 04510, DF, Mexico

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 05期

关键词：

SOFT ACIDS; BASES PRINCIPLE; HARDNESS; MOLECULES;

D O I：

10.1021/ol103011h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It has been suggested that pyridine and pyrrole could be patterns for imidazole reactivity studies due to the amine (-NH-) and aza (-NH=) nitrogen atoms. The analyses of the local and global electronic indexes prove and quantify that imidazole has an intermediate analogy between pyrrole and pyridine.

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收藏

页码：972 / 975

页数：4

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