Synthesis and crystal structures of thiolate-bridged diruthenium complexes containing two olefinic ligands

被引：7
|
作者：
Qu, JP [1 ]
Matsuzaka, H [1 ]
Ishii, Y [1 ]
Hidai, M [1 ]
机构：
[1] UNIV TOKYO, GRAD SCH ENGN, DEPT CHEM & BIOTECHNOL, BUNKYO KU, TOKYO 113, JAPAN
来源：
CHEMISTRY LETTERS | 1996年 / 09期
关键词：
D O I：
10.1246/cl.1996.767
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of thiolate-bridged dinuclear ruthenium complexes containing two electron-deficient olefinic ligands [Cp*Ru(mu-SR)(2)(eta(2)-C(2)H(3)R')(2)RuCp*] (R = Pr-i, Et, 2,6-C(6)H(3)Me(2) or 2,4,6-C(6)H(2)Me(3); R' = CN, COOMe or CHO) have been synthesized from Ru(II)-Ru(II), Ru(II)-Ru(III) and/or Ru(III)-Ru(III) precursors, three of which have been characterized by X-ray structural analysis.
引用
收藏
页码：767 / 768
页数：2
相关论文
共 50 条
  • [11] Novel propargylic substitution reactions catalyzed by thiolate-bridged diruthenium complexes via allenylidene intermediates
    Nishibayashi, Y
    Wakiji, I
    Hidai, M
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (44) : 11019 - 11020
  • [12] Head-to-head Z dimerization of terminal alkynes catalyzed by thiolate-bridged diruthenium complexes
    Qü, JP
    Masui, D
    Ishii, Y
    Hidai, M
    CHEMISTRY LETTERS, 1998, (10) : 1003 - 1004
  • [13] Thiolate-Bridged Heterodinuclear Manganese-Cobalt Complexes with Bridging Hydride Ligands
    Pathak, Kriti
    Mishra, Shivankan
    Bairagi, Subhash
    Rajeshwaree, B.
    Dutta, Arnab
    Ghosh, Sundargopal
    ORGANOMETALLICS, 2023, 42 (02) : 133 - 145
  • [14] NOVEL REACTIONS OF ALKYNES ON A COORDINATIVELY UNSATURATED DIRUTHENIUM CENTER BRIDGED BY THIOLATE LIGANDS - SYNTHESES AND CRYSTAL-STRUCTURES OF DINUCLEAR RUTHENACYCLOPENTENYL COMPLEXES
    NISHIO, M
    MATSUZAKA, H
    MIZOBE, Y
    HIDAI, M
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (04) : 375 - 377
  • [15] Thiolate-Bridged Dicobalt Complexes Bearing Hydrazine, Hydrazido, and Diazenido Ligands: Synthesis, Structural Characterization, and Interconversion
    Li, Jianzhe
    Yang, Dawei
    Tong, Peng
    Wang, Chunlong
    Wang, Baomin
    Qu, Jingping
    INORGANIC CHEMISTRY, 2020, 59 (12) : 8203 - 8212
  • [16] COUPLING OF PROPARGYL ALCOHOLS VIA ALLENYLIDENE ALKYNYL OR VINYLVINYLIDENE ALKYNYL COMBINATION ON A THIOLATE-BRIDGED DIRUTHENIUM CENTER - SYNTHESES AND CRYSTAL-STRUCTURES OF DIRUTHENACYCLOPENTANONE AND DIRUTHENACYCLOPENTENONE COMPLEXES
    MATSUZAKA, H
    KOIZUMI, H
    TAKAGI, Y
    NISHIO, M
    HIDAI, M
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (22) : 10396 - 10397
  • [17] Catalytic Activity of Thiolate-Bridged Diruthenium Complexes Bearing Pendent Ether Moieties in the Oxidation of Molecular Dihydrogen
    Yuki, Masahiro
    Sakata, Ken
    Kikuchi, Shoma
    Kawai, Hiroyuki
    Takahashi, Tsuyoshi
    Ando, Masaki
    Nakajima, Kazunari
    Nishibayashi, Yoshiaki
    CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (05) : 1007 - 1012
  • [18] SILYLATIVE DIMERIZATION OF AROMATIC-ALDEHYDES CATALYZED BY A THIOLATE-BRIDGED DIRUTHENIUM COMPLEX
    SHIMADA, H
    QU, JP
    MATSUZAKA, H
    ISHII, Y
    HIDAI, M
    CHEMISTRY LETTERS, 1995, (08) : 671 - 672
  • [19] Hydration of Nitriles to Amides by Thiolate-Bridged Diiron Complexes
    Tong, Peng
    Yang, Dawei
    Li, Yang
    Wang, Baomin
    Qu, Jingping
    ORGANOMETALLICS, 2015, 34 (14) : 3571 - 3576
  • [20] Catalytic disproportionation of hydrazine by thiolate-bridged diiron complexes
    Su, Linan
    Yang, Dawei
    Wang, Baomin
    Qu, Jingping
    INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 112
12345