High-nuclearity homometallic iron and nickel clusters:: Fe22 and Ni24 complexes from the use of N-methyldiethanolamine

被引：126

作者：

Foguet-Albiol, D ^{[1
]}

Abboud, KA ^{[1
]}

Christou, G ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 34期

关键词：

D O I：

10.1039/b507748f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of N-methyldiethanolamine (mdaH(2)) in reactions with Fe(III) and Ni(II) sources has led to Fe-22 and Ni-24 products; the clusters are the highest and second-highest, respectively, homometallic clusters for these metals to date, and possess S = 0 and S = 6 ground states, respectively.

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页码：4282 / 4284

页数：3

相关论文

共 16 条

[1] THE SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A CYCLIC DODECANUCLEAR NICKEL-COMPLEX [J].

BLAKE, AJ ;

GRANT, CM ;

PARSONS, S ;

RAWSON, JM ;

WINPENNY, REP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (20) :2363-2364

[2] Methanolysis and phenolysis routes to Fe6, Fe8, and Fe10 complexes and their magnetic properties:: A new type of Fe8 ferric wheel [J].

Cañada-Vilalta, C ;

O'Brien, TA ;

Pink, M ;

Davidson, ER ;

Christou, G .

INORGANIC CHEMISTRY, 2003, 42 (24) :7819-7829

[3]

Dearden AL, 2001, ANGEW CHEM INT EDIT, V40, P151, DOI 10.1002/1521-3773(20010105)40:1<151::AID-ANIE151>3.0.CO

[4]

2-S

[5] NEW CO AND NI CLUSTERS WITH SE AND PPH3 AS LIGANDS - [CO4(MU-3SE)4(PPH3)4], [CO6(MU-3-SE)8(PPH3)6], [CO9(MU-4-SE)3(MU-3-SE)8(PPH3)6], AND "[NI34(MU-5-SE)2(MU-4-SE)20(PPH3)10] [J].

FENSKE, D ;

OHMER, J ;

HACHGENEI, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (11) :993-995

[6] DFT computational rationalization of an unusual spin ground state in an Mn12 single-molecule magnet with a low-symmetry loop structure [J].

Foguet-Albiol, D ;

O'Brien, TA ;

Wernsdorfer, W ;

Moulton, B ;

Zaworotko, MJ ;

Abboud, KA ;

Christou, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (06) :897-901

[7] OXO-BRIDGED AND HYDROXO-BRIDGED DIIRON COMPLEXES - A CHEMICAL PERSPECTIVE ON A BIOLOGICAL UNIT [J].

KURTZ, DM .

CHEMICAL REVIEWS, 1990, 90 (04) :585-606

[8] Preparation and properties of new Fe6 and Fe8 clusters of iron(III) with tripodal ligands [J].

Murugesu, M ;

Abboud, KA ;

Christou, G .

DALTON TRANSACTIONS, 2003, (23) :4552-4556

[9] Single-molecule magnets:: A Mn25 complex with a record S=51/2 spin for a molecular species [J].

Murugesu, M ;

Habrych, M ;

Wernsdorfer, W ;

Abboud, KA ;

Christou, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (15) :4766-4767

[10] New structural motifs in manganese single-molecule magnetism from the use of triethanolamine ligands [J].

Murugesu, M ;

Wernsdorfer, F ;

Abboud, KA ;

Christou, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (06) :892-896