Copper(II) complexes with a novel tris(3,5-diisopropyl-1-pyrazolyl)methane ligand, [Cu(X2){HC(3,5-iPr2pz)3}](X=Cl and NO3)

被引:25
|
作者
Fujisawa, K
Ono, T
Aoki, H
Ishikawa, Y
Miyashita, Y
Okamoto, K
Nakazawa, H
Higashimura, H
机构
[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
[2] Osaka City Univ, Dept Chem, Osaka 5588585, Japan
[3] Sumitomo Chem Co Ltd, Tsukuba Res Lab, Tsukuba, Ibaraki 3003294, Japan
基金
日本学术振兴会;
关键词
copper(II); hydrotris(pyrazolyl)borate; tris(pyrazolyl)methane; mononuclear complex; crystal structure;
D O I
10.1016/j.inoche.2003.12.005
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of a novel tris(3,5-diisopropyl-1-pyrazolyl)methane ligand, HC(3,5-(i)Pr(2)pz)(3), is described; the structures of chlorocopper(II) and nitratocopper(II) complexes with its ligand have been determined by X-ray crystallography and compared with those of the related copper(II) complexes with HB(3,5-(i)Pr(2)pz)(3)(-) (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:330 / 332
页数:3
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