Transition-metal-free, visible-light-mediated cyclization of o-azidoarylalkynes with aryl diazonium salts

被引：23

作者：

Jin, Cheng ^{[1
]}

Su, Lianzheng ^{[2
]}

Ma, Daxi ^{[3
]}

Cheng, Mingrong ^{[4
]}

机构：

[1] New United Grp Co Ltd, Changzhou 213166, Jiangsu, Peoples R China

[2] Jiangsu Vcare Pharmatech Co Ltd, Nanjing 211800, Jiangsu, Peoples R China

[3] Shanghai Univ Med & Hlth Sci, Affiliated Zhoupu Hosp, Dept Gen Surg, Shanghai 201318, Peoples R China

[4] Tongji Univ, Tianyou Hosp, Dept Gen Surg, Shanghai 200000, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 23期

关键词：

C-H ARYLATION; INDOLE SYNTHESIS; ARYLSULFONYL CHLORIDES; REGIOSPECIFIC ROUTE; N-H; ALKYNES; ANNULATION; CHEMISTRY; EFFICIENT;

D O I：

10.1039/c7nj03144k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Visible light along with 3 mol% eosin Y catalyzes the cyclization reaction of o-azidoarylalkynes with aryl diazonium salts by a photo-redox process. We have investigated the scope of the reaction for several aryl diazonium salts and o-azidoarylalkynes. The general and easy procedure provides a transition-metal-free alternative for the formation of unsymmetrical 2,3-diaryl-substitued indoles.

引用

页码：14053 / 14056

页数：4

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