A Self-Healing Aqueous Lithium-Ion Battery

被引：209

作者：

Zhao, Yang ^{[1
,2
]}

Zhang, Ye ^{[1
,2
]}

Sun, Hao ^{[1
,2
]}

Dong, Xiaoli ^{[3
,4
]}

Cao, Jingyu ^{[1
,2
]}

Wang, Lie ^{[1
,2
]}

Xu, Yifan ^{[1
,2
]}

Ren, Jing ^{[1
,2
]}

Hwang, Yunil ^{[5
]}

Son, In Hyuk ^{[5
]}

Huang, Xianliang ^{[6
]}

Wang, Yonggang ^{[3
,4
]}

Peng, Huisheng ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, Shanghai 200438, Peoples R China

[2] Fudan Univ, Adv Mat Lab, Shanghai 200438, Peoples R China

[3] Fudan Univ, Dept Chem, Shanghai 200438, Peoples R China

[4] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Inst New Energy, IChEM Collaborat Innovat Ctr Chem Energy Mat, Shanghai 200438, Peoples R China

[5] Samsung Elect Co LTD, Energy Mat Lab, Mat Res Ctr, Samsung Adv Inst Technol, 130 Samsung Ro, Suwon 443803, Gyeonggi Do, South Korea

[6] Samsung R&D Inst China, Beijing 100028, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2016年 / 55卷 / 46期

关键词：

carbon nanotubes; flexible electronics; lithium-ion batteries; nanotechnology; self-healing polymers; SUPERIONIC CONDUCTORS; ROOM-TEMPERATURE; HIGH-POWER; SUPERCAPACITOR; ELECTROLYTES; DESIGN; CELLS; THIN;

D O I：

10.1002/anie.201607951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flexible lithium-ion batteries are critical for the next-generation electronics. However, during the practical application, they may break under deformations such as twisting and cutting, causing their failure to work or even serious safety problems. A new family of all-solid-state and flexible aqueous lithium ion batteries that can self-heal after breaking has been created by designing aligned carbon nanotube sheets loaded with LiMn2O4 and LiTi2(PO4)(3) nanoparticles on a self-healing polymer substrate as electrodes, and a new kind of lithium sulfate/sodium carboxymethylcellulose serves as both gel electrolyte and separator. The specific capacity, rate capability, and cycling performance can be well maintained after repeated cutting and self-healing. These self-healing batteries are demonstrated to be promising for wearable devices.

引用

页码：14382 / 14386

页数：5

共 40 条

[21] Bendable and Thin Sulfide Solid Electrolyte Film: A New Electrolyte Opportunity for Free-Standing and Stackable High-Energy All-Solid-State Lithium-Ion Batteries [J].