Synthesis, Photoluminescence, and Magnetic Properties of Nitrogen-Doping Helical Carbon Nanotubes

被引:37
作者
Wen, Jianfeng [1 ]
Zhang, Yang [1 ]
Tang, Nujiang [1 ]
Wan, Xiangang [1 ]
Xiong, Zhuhong [2 ]
Zhong, Wei [1 ]
Wang, Zhenlin [1 ]
Wu, Xinglong [1 ]
Du, Youwei [1 ]
机构
[1] Nanjing Univ, Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China
[2] Southwest Univ, Sch Phys Sci & Technol, Chongqing 400715, Peoples R China
关键词
LARGE-SCALE SYNTHESIS; ROOM-TEMPERATURE; ULTRAVIOLET EMISSION; CNX NANOTUBES; NANOFIBERS; GRAPHENE; SINGLE; GROWTH; BORON; NANOCOMPOSITES;
D O I
10.1021/jp202723f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Over Ni nanoparticles generated by means of a combined sol-gel/reduction method, helical carbon nanotubes (HCNTs) were synthesized in acetylene pyrolysis at 425 degrees C. By annealing the pristine HCNTs in NH3 atmosphere, the N-doped HCNTs were obtained. The dependence of annealing temperature on the nitrogen content and doping type of the N-doped HCNTs was studied. The photoluminescence (PL) properties of the pristine HCNTs and N-doped HCNTs were examined systematically at room temperature (RT). The results demonstrated that the pristine HCNTs exhibit strong ultraviolet (UV) PL at 368 nm. By doping the pyridinic and graphitic N into the pristine HCNTs, the UV PL could be enhanced. Moreover, the magnetic properties of the pristine and N-doped HCNTs have been measured.
引用
收藏
页码:12329 / 12334
页数:6
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