Synthesis, Photoluminescence, and Magnetic Properties of Nitrogen-Doping Helical Carbon Nanotubes

被引:37
作者
Wen, Jianfeng [1 ]
Zhang, Yang [1 ]
Tang, Nujiang [1 ]
Wan, Xiangang [1 ]
Xiong, Zhuhong [2 ]
Zhong, Wei [1 ]
Wang, Zhenlin [1 ]
Wu, Xinglong [1 ]
Du, Youwei [1 ]
机构
[1] Nanjing Univ, Nanjing Natl Lab Microstruct, Nanjing 210093, Peoples R China
[2] Southwest Univ, Sch Phys Sci & Technol, Chongqing 400715, Peoples R China
关键词
LARGE-SCALE SYNTHESIS; ROOM-TEMPERATURE; ULTRAVIOLET EMISSION; CNX NANOTUBES; NANOFIBERS; GRAPHENE; SINGLE; GROWTH; BORON; NANOCOMPOSITES;
D O I
10.1021/jp202723f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Over Ni nanoparticles generated by means of a combined sol-gel/reduction method, helical carbon nanotubes (HCNTs) were synthesized in acetylene pyrolysis at 425 degrees C. By annealing the pristine HCNTs in NH3 atmosphere, the N-doped HCNTs were obtained. The dependence of annealing temperature on the nitrogen content and doping type of the N-doped HCNTs was studied. The photoluminescence (PL) properties of the pristine HCNTs and N-doped HCNTs were examined systematically at room temperature (RT). The results demonstrated that the pristine HCNTs exhibit strong ultraviolet (UV) PL at 368 nm. By doping the pyridinic and graphitic N into the pristine HCNTs, the UV PL could be enhanced. Moreover, the magnetic properties of the pristine and N-doped HCNTs have been measured.
引用
收藏
页码:12329 / 12334
页数:6
相关论文
共 52 条
[1]   ELECTRONIC-STRUCTURE OF HELICALLY COILED CAGE OF GRAPHITIC CARBON [J].
AKAGI, K ;
TAMURA, R ;
TSUKADA, M ;
ITOH, S ;
IHARA, S .
PHYSICAL REVIEW LETTERS, 1995, 74 (12) :2307-2310
[2]   A FORMATION MECHANISM FOR CATALYTICALLY GROWN HELIX-SHAPED GRAPHITE NANOTUBES [J].
AMELINCKX, S ;
ZHANG, XB ;
BERNAERTS, D ;
ZHANG, XF ;
IVANOV, V ;
NAGY, JB .
SCIENCE, 1994, 265 (5172) :635-639
[3]   Tailoring N-doped single and double wall carbon nanotubes from a nondiluted carbon/nitrogen feedstock [J].
Ayala, Paola ;
Grueneis, Alexander ;
Gemming, Thomas ;
Grimm, Daniel ;
Kramberger, Christian ;
Ruemmeli, Mark H. ;
Freire, Fernando L., Jr. ;
Kuzmany, Hans ;
Pfeiffer, Rudolf ;
Barreiro, Amelia ;
Buechner, Bernd ;
Pichler, Thomas .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (07) :2879-2884
[4]   Large-scale synthesis of perpendicularly aligned helical carbon nanotubes [J].
Bajpai, V ;
Dai, LM ;
Ohashi, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (16) :5070-5071
[5]   Grain size effects on the magnetic properties of chemically synthesized Ni:Ni3C nanocomposites [J].
Bonder, MJ ;
Kirkpatrick, EM ;
Martin, T ;
Kim, SJ ;
Rieke, RD ;
Leslie-Pelecky, DL .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2000, 222 (1-2) :70-78
[6]   Origin of the large N is binding energy in X-ray photoelectron spectra of calcined carbonaceous materials [J].
Casanovas, J ;
Ricart, JM ;
Rubio, J ;
Illas, F ;
JimenezMateos, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (34) :8071-8076
[7]   Synergism of C5N six-membered ring and vapor-liquid-solid growth of CNx nanotubes with pyridine precursor [J].
Chen, Hong ;
Yang, Yong ;
Hu, Zheng ;
Huo, Kaifu ;
Ma, Yanwen ;
Chen, Yi ;
Wang, Xiaoshu ;
Lu, Yinong .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (33) :16422-16427
[8]   Optical and Excitonic Properties of Crystalline ZnS Nanowires: Toward Efficient Ultraviolet Emission at Room Temperature [J].
Chen, Rui ;
Li, Dehui ;
Liu, Bo ;
Peng, Zeping ;
Gurzadyan, Gagik G. ;
Xiong, Qihua ;
Sun, Handong .
NANO LETTERS, 2010, 10 (12) :4956-4961
[9]   Mechanics of a carbon nanocoil [J].
Chen, XQ ;
Zhang, SL ;
Dikin, DA ;
Ding, WQ ;
Ruoff, RS ;
Pan, LJ ;
Nakayama, Y .
NANO LETTERS, 2003, 3 (09) :1299-1304
[10]   Mechanical properties of nanosprings [J].
da Fonseca, AF ;
Galvao, DS .
PHYSICAL REVIEW LETTERS, 2004, 92 (17) :175502-1