Simple, but Challenging: Recent Developments in the Asymmetric Synthesis of Spiroketals

被引：37
作者：
Wilsdorf, Michael [1 ]
Reissig, Hans-Ulrich [1 ]
机构：
[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 38期
关键词：
asymmetric catalysis; natural products; organocatalysis; spiroketals; ENANTIOSELECTIVE HYDROGENATION; NATURAL-PRODUCTS; (+/-)-GAMMA-RUBROMYCIN; KETONES; SPANPHOS;
D O I：
10.1002/anie.201203847
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Impressive and elegant approaches to the enantioselective synthesis of spiroketals starting from achiral substrates have been described recently. These strategies based on transition-metal catalysis and organocatalysis hold great potential for further applications. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：9486 / 9488
页数：3
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