Comparing the Pyrophoricity of Palladium Catalysts for Heterogeneous Hydrogenation

被引:13
作者
Cote, Carlos Ramirez [1 ]
Ciriminna, Rosaria [2 ]
Pandarus, Valerica [1 ]
Beland, Francois [1 ]
Pagliaro, Mario [2 ]
机构
[1] SiliCycle, 2500 Parc Technol Blvd, Quebec City, PQ G1P 4S6, Canada
[2] CNR, Ist Studio Mat Nanostrutturati, Via U La Malfa 153, I-90146 Palermo, Italy
关键词
pyrophoric; palladium; heterogeneous; hydrogenation; hydrogenolysis; HYDROGENOLYSIS;
D O I
10.1021/acs.oprd.8b00242
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
We compare the pyrophoricity of two commonly employed hydrogenation and hydrogenolysis palladium solid catalysts, Pd/C and SiliaCat Pd-0, and the reactivity of SiliaCat Pd-0 with that of two commercial hydrogenation catalysts (Pt-0 EnCat and Pd/C) in the hydrogenation of six different nitroarene compounds under optimized reaction conditions.
引用
收藏
页码:1852 / 1855
页数:4
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