AlCl3•6H2O as a Catalyst for Simple and Efficient Synthesis of gem-Dihydroperoxides from Ketones and Aldehydes using Aqueous H2O2

被引：14

作者：

Azarifar, D. ^{[1
]}

Khosravi, K. ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Dept Chem, Hamadan 65178, Iran

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2011年 / 8卷 / 04期

关键词：

gem-Dihydroperoxides; Aluminium chloride hexahydrate; AlCl3 center dot 6H(2)O; Ketones; Aldehydes; Aqueous H2O2; ANTIMALARIAL ACTIVITY; HYDROGEN-PEROXIDE; GEMINAL BISHYDROPEROXIDES; CYCLOHEXYLIDENEBISHYDROPEROXIDE; 1,2,4,5-TETRAOXACYCLOALKANES; DISPIRO-1,2,4,5-TETRAOXANES; HYDROPEROXIDE; DERIVATIVES; EPOXIDATION; IODINE;

D O I：

10.1007/BF03246556

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

AlCl3 center dot 6H(2)O was explored as an efficient catalyst for the synthesis of gem-dihydroperoxides (DHPs) from ketones and aldehydes. The reactions took place within a short period of time using (30%) aqueous H2O2 as a "green" oxidant in acetonitrile under neutral conditions at room temperature to afford the products in high yields.

引用

页码：1006 / 1013

页数：8

共 48 条

[1]

Adam W., 2000, PEROXIDE CHEM MECH P

[2]

Ando W., 1992, Organic peroxides

[3]

Azarifar D., 2010, Eur J. Chem. Soc, V1, P15, DOI DOI 10.5155/EURJCHEM.1.1.15-19.6

[4] SYNTHESIS OF 1,2-DISUBSTITUTED BENZIMIDAZOLES AND 2-SUBSTITUTED BENZOTHIAZOLES CATALYZED BY HCl-TREATED TRANS-3,5-DIHYDROPEROXY-3,5-DIMETHYL-1,2-DIOXOLANE [J].