Coupling of epoxides and carbon dioxide catalyzed by Bronsted acid ionic liquids

被引：41
|
作者：
Chang, Tao [1 ]
Gao, Xiaorui [1 ]
Bian, Li [1 ]
Fu, Xiying [1 ]
Yuan, Mingxia [1 ]
Jing, Huanwang [2 ]
机构：
[1] Hebei Univ Engn, Coll Sci, Engn Lab Coalbed Gas Exploitat Hebei Prov, Handan 056038, Hebei, Peoples R China
[2] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
来源：
CHINESE JOURNAL OF CATALYSIS | 2015年 / 36卷 / 03期
基金：
中国国家自然科学基金;
关键词：
Carbon dioxide fixation; Coupling reaction; Bronsted acidic ionic liquid; Cyclic carbonate; Hammett acidity; CYCLIC CARBONATES; BIFUNCTIONAL CATALYSTS; QUATERNIZED CHITOSAN; EFFICIENT CATALYSTS; MANNICH REACTION; CO2; FIXATION; CYCLOADDITION; COMPLEXES; GREEN;
D O I：
10.1016/S1872-2067(14)60227-8
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A series of Bronsted acid ionic liquids (BAILS) containing a long chain Bronsted acid site in the cationic part and a Lewis basic site in the anionic part were designed, synthesized, and used as catalyst for the coupling of epoxides and carbon dioxide to cyclic carbonates without a co-catalyst or co-solvent. The effects of catalyst structure and other parameters on the catalytic performance were investigated. The long chain 2-(N,N-dimethyldodecylammonium) acetic acid bromide ([(CH2COOH)DMDA]Br) showed high catalytic activity and good reusability. This protocol was expanded to various epoxides, which gave the corresponding cyclic carbonates in good yields. The acidity of the catalyst influenced its catalytic activity. (C) 2015, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：408 / 413
页数：6
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