Group 10 metal-cyanide scaffolds in complexes and extended frameworks: Properties and applications

被引：23

作者：

Sadeghian, Mina ^{[1
]}

Haghighi, Mohsen Golbon ^{[1
]}

Lalinde, Elena ^{[2
]}

Teresa Moreno, M. ^{[2
]}

机构：

[1] Shahid Beheshti Univ, Dept Chem, Tehran 1983969411, Iran

[2] Univ La Rioja, Dept Quim, Ctr Sintesis Quim Rioja CISQ, Logrono 26006, Spain

来源：

COORDINATION CHEMISTRY REVIEWS | 2022年 / 452卷

关键词：

Cyanide; Transition metals of Group 10; Luminescence; Coordination polymers; Catalyst; Magnetism; PRUSSIAN BLUE ANALOGS; CENTER-DOT-PT; NEGATIVE THERMAL-EXPANSION; ALLOY NETWORK NANOSTRUCTURES; PLATINUM-THALLIUM COMPOUNDS; RAY CRYSTAL-STRUCTURE; SPIN-CROSSOVER; HOFMANN-TYPE; SOLID-STATE; COORDINATION POLYMERS;

D O I：

10.1016/j.ccr.2021.214310

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

To date, group 10 metal-cyanide scaffolds as promising candidates in the form of discrete organometallic complexes or one-, two-and three-dimensional coordination polymers have been attracted considerable attention due to their interesting properties and potential applications in many fields from medicine to materials science. In this review, cyanide compounds, according to structural, physical, chemical, and optical properties, were classified and various applications, based on the number of connected cyanide ligands to these metals, such as luminescence, porosity, halogen or hydrogen-bond acceptors, negative thermal expansion, nanostructures, magnetism, catalyst, and medicine were discussed. (c) 2021 Elsevier B.V. All rights reserved.

引用

页数：60

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