Mix and match metal oxides and nanocarbons for new photocatalytic frontiers

被引:27
作者
Melchionna, Michele [1 ]
Prato, Maurizio [1 ,2 ,3 ]
Fornasiero, Paolo [1 ,4 ]
机构
[1] Univ Trieste, INSTM, Dept Chem & Pharmaceut Sci, Via L Giorgieri 1, I-34127 Trieste, Italy
[2] CIC biomaGUNE, Carbon Nanobiotechnol Lab, Paseo Miramon 182, Donostia San Sebastian 20009, Spain
[3] Ikerbasque, Basque Fdn Sci, Bilbao 48013, Spain
[4] Univ Trieste, ICCOM CNR, Via L Giorgieri 1, I-34127 Trieste, Italy
关键词
Hybrid photocatalysts; Metal oxides; Nanocarbons; Carbon nanotubes; Graphene; WALLED CARBON NANOTUBES; ANCHORING SEMICONDUCTOR; HYDROGEN-PRODUCTION; TIO2; NANOPARTICLES; METHYLENE-BLUE; GRAPHENE; NANOCOMPOSITES; DEGRADATION; COMPOSITES; ZNO;
D O I
10.1016/j.cattod.2016.04.024
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Hybridization of metal oxides with nanocarbons has become a very fertile soil of research, given the synergy of the two phases that results in most cases in an improved photo-catalytic performance. Despite the mechanism is still uncertain, it has been established that the presence of a nanocarbon can retard recombination of the photo-excited electrons and holes. The improved activity critically depends on the method of synthesis, which should be designed as to have the maximum C-metal oxide contact. Much research has been conducted on graphene and carbon nanotubes, but other carbon structures are slowly coming to surface. The vast majority of reports focuses on photo-degradation of organic contaminants, but application to energy related fields is becoming more and more popular. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:202 / 213
页数:12
相关论文
共 82 条
[1]   H2 production by selective photo-dehydrogenation of ethanol in gas and liquid phase on CuOx/TiO2 nanocomposites [J].
Ampelli, Claudio ;
Passalacqua, Rosalba ;
Genovese, Chiara ;
Perathoner, Siglinda ;
Centi, Gabriele ;
Montini, Tiziano ;
Gombac, Valentina ;
Delgado Jaen, Juan Jose ;
Fornasiero, Paolo .
RSC ADVANCES, 2013, 3 (44) :21776-21788
[2]   Reaction Mechanism and Activity of WO3-Catalyzed Photodegradation of Organic Substances Promoted by a CuO Cocatalyst [J].
Arai, Takeo ;
Horiguchi, Masumi ;
Yanagida, Masatoshi ;
Gunji, Takahiro ;
Sugihara, Hideki ;
Sayama, Kazuhiro .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (16) :6602-6609
[3]   TiO2 nanotubes and CNT-TiO2 hybrid materials for the photocatalytic oxidation of propene at low concentration [J].
Bouazza, N. ;
Ouzzine, M. ;
Lillo-Rodenas, M. A. ;
Eder, D. ;
Linares-Solano, A. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 92 (3-4) :377-383
[4]   Glossary of terms used in photocatalysis and radiation catalysis (IUPAC Recommendations 2011) [J].
Braslavsky, Silvia E. ;
Braun, Andre M. ;
Cassano, Alberto E. ;
Emeline, Alexei V. ;
Litter, Marta I. ;
Palmisano, Leonardo ;
Parmon, Valentin N. ;
Serpone, Nick ;
Alfano, O. M. ;
Anpo, M. ;
Augugliaro, V. ;
Bohne, C. ;
Esplugas, S. ;
Oliveros, E. ;
von Sonntag, C. ;
Weiss, R. G. ;
Schiavello, M. .
PURE AND APPLIED CHEMISTRY, 2011, 83 (04) :931-1014
[5]   Hydrothermal preparation of ZnO:CNT and TiO2:CNT composites and their photocatalytic applications [J].
Byrappa, K. ;
Dayananda, A. S. ;
Sajan, C. P. ;
Basavalingu, B. ;
Shayan, M. B. ;
Soga, K. ;
Yoshimura, M. .
JOURNAL OF MATERIALS SCIENCE, 2008, 43 (07) :2348-2355
[6]   Multiwalled Carbon Nanotubes Drive the Activity of Metal@oxide Core-Shell Catalysts in Modular Nanocomposites [J].
Cargnello, Matteo ;
Grzelczak, Marek ;
Rodriguez-Gonzalez, Benito ;
Syrgiannis, Zois ;
Bakhmutsky, Kevin ;
La Parola, Valeria ;
Liz-Marzan, Luis M. ;
Gorte, Raymond J. ;
Prato, Maurizio ;
Fornasiero, Paolo .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (28) :11760-11766
[7]   Photoinduced reactivity of titanium dioxide [J].
Carp, O ;
Huisman, CL ;
Reller, A .
PROGRESS IN SOLID STATE CHEMISTRY, 2004, 32 (1-2) :33-177
[8]   Enhanced visible light-induced photoelectrocatalytic degradation of phenol by carbon nanotube-doped TiO2 electrodes [J].
Chen, Lung-Chuan ;
Ho, Yi-Ching ;
Guo, Wei-Sheng ;
Huang, Chao-Ming ;
Pan, Ting-Chung .
ELECTROCHIMICA ACTA, 2009, 54 (15) :3884-3891
[9]  
Chuan-Yu Y, 2008, NANOTECHNOLOGY, V19
[10]   Chemical oxidation of multiwalled carbon nanotubes [J].
Datsyuk, V. ;
Kalyva, M. ;
Papagelis, K. ;
Parthenios, J. ;
Tasis, D. ;
Siokou, A. ;
Kallitsis, I. ;
Galiotis, C. .
CARBON, 2008, 46 (06) :833-840