Thermal Decomposition of Cationic, Anionic, and Double Complex Compounds of 3d-Metals

被引：7

作者：

Pechenyuk, S. I. ^{[1
]}

Domonov, D. P. ^{[1
]}

Gosteva, A. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Kola Sci Ctr, IV Tananaev Inst Chem & Technol Rare Elements & M, Apatity 184209, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2021年 / 91卷 / 09期

关键词：

3d-metals; complex compounds; central ions; ligands; thermal decomposition; thermolysis products; LANTHANUM HEXACYANOCOBALTATE(III) PENTAHYDRATE; X-RAY-ANALYSIS; CRYSTAL-STRUCTURE; METAL-COMPLEXES; MAGNETIC-PROPERTIES; CYANO COMPLEXES; ETHYLENEDIAMINE COMPLEXES; MICROSTRUCTURAL CHANGES; BIMETALLIC ASSEMBLIES; THERMOLYSIS PRODUCTS;

D O I：

10.1134/S1070363221090310

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review deals with the thermal behavior of cationic, anionic, and double complex compounds of 3d-metals (Fe, Co, Ni, Cu, Mn, and Cr) in comparison with complexes of noble metals, with coordinated ammonia, organic amines, urea, cyanide, thiocyanate, oxalate, and nitrite. It is shown that in the thermolysis process carried out under non-equilibrium conditions, double complexes can withstand heating up to 200-250 degrees C, regardless of their thermodynamic stability.

引用

页码：1834 / 1861

页数：28

共 172 条

[1] Crystallographic characterization and NO2 gas sensing property of LnFeO3 prepared by thermal decomposition of Ln-Fe hexacyanocomplexes, Ln[Fe(CN)6]•nH2O, Ln = La, Nd, Sm, Gd, and Dy [J].