Effect of phosphoric acid and acetic acid addition on the hydrogen evolution using Ni based catalyst prepared in ethanol, methanol, and water solvents

被引：14

作者：

Balbay, Asim ^{[1
]}

Saka, Cafer ^{[2
]}

机构：

[1] Siirt Univ, Fac Engn & Architecture, Siirt, Turkey

[2] Siirt Univ, Sch Hlth, TR-56100 Siirt, Turkey

来源：

ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS | 2018年 / 40卷 / 20期

关键词：

Acetic acid; ethanol; nickel catalyst; phosphoric acid; sodium borohydride; SODIUM-BOROHYDRIDE; NABH4; HYDROLYSIS; PLASMA TREATMENT; BORIDE CATALYST; LACTIC-ACID; GENERATION; NICKEL; COBALT; NANOPARTICLES; CONVERSION;

D O I：

10.1080/15567036.2018.1502841

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Ni-based catalysts were synthesized in water, methanol and ethanol solvents by chemical reduction with sodium borohydride (NaBH4). The obtained catalyst for the first time was used to catalyze the NaBH4 hydrolysis reaction with phosphoric acid and acetic acid including different concentrations. The maximum hydrogen production rates obtained in the hydrolysis reaction including 0.5M phosphoric acid and 0.1M acetic acid of the Ni-based catalyst prepared in ethanol solvent were 5214 and 3650ml g(-1)min(-1), respectively.

引用

页码：2442 / 2450

页数：9

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