Solving the Poisson-Boltzmann equation for two parallel cylinders

被引:35
|
作者
Harries, D [1 ]
机构
[1] Hebrew Univ Jerusalem, Dept Phys Chem, IL-91904 Jerusalem, Israel
[2] Hebrew Univ Jerusalem, Fritz Haber Res Ctr, IL-91904 Jerusalem, Israel
关键词
D O I
10.1021/la971314b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrostatic interaction between two parallel charged cylinders of arbitrary diameters alpha(1) and alpha(2) is studied by solving numerically the nonlinear Poisson-Boltzmann equation. A limit of particular interest is that of a charged cylinder interacting with a charged plane (alpha(1) --> infinity). The interaction free energy is calculated, as a function of the separation distance between the cylinders, for either fixed charge density or mixed (fixed charge, fixed potential) boundary conditions.
引用
收藏
页码:3149 / 3152
页数:4
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