Synthesis of nitrogen-doped mesoporous carbon nanosheets for oxygen reduction electrocatalytic activity enhancement in acid and alkaline media

被引：18
作者：
Lei, Hui-yu [1 ]
Piao, Jin-hua [2 ]
Brouzgou, Angeliki [5 ]
Gorbova, Elena [3 ,4 ,5 ]
Tsiakaras, Panagiotis [3 ,4 ,5 ]
Liang, Zhen-xing [1 ]
机构：
[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China
[2] South China Univ Technol, Sch Food Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China
[3] RAS, Inst High Temp Electrochem, Lab Electrochem Devices Based Solid Oxide Proton, Ekaterinburg 620990, Russia
[4] Ural Fed Univ, Lab Mat & Devices Electrochem Power Ind, 19 Mira St, Ekaterinburg 620002, Russia
[5] Univ Thessaly, Sch Engn, Dept Mech Engn, Lab Alternat Energy Convers Syst, Volos 38334, Volos, Greece
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2019年 / 44卷 / 09期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
Oxygen reduction reaction; Mesoporous silica film; Nitrogen-doped mesoporous carbon nanosheet; Electrochemical devices; HIGHLY EFFICIENT; TEMPLATED SYNTHESIS; GRAPHENE; MCM-48; CATALYST; PYROLYSIS; INSIGHT; SILICA; SHEETS; BLACK;
D O I：
10.1016/j.ijhydene.2018.11.096
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the present work, nitrogen-doped mesoporous carbon nanosheets (NMCNs) are prepared and extensively investigated for the oxygen reduction reaction. Initially, by using dual templates, viz. graphene oxide and a cationic surfactant, silica films (thickness: 1.0 nm) are synthesized and characterized using transmission electron microscope (TEM), nitrogen adsorption-desorption (N-2 ad/des) measurements, and small-angle X-ray diffraction (SA-XRD). Morphology and structure of silica evolve along with graphene oxide concentration, while the co-operative assembly and the final structure are determined by the electrostatic interaction between the dual templates. The effect of silica template on the resultant NMCNs is investigated physicochemically by photoelectron spectroscopy (XPS), TEM, N-2 ad/des and electrochemically by cyclic voltammetry (CV), and linear sweep voltammetry (LSV). NMCNs are featured of a high content of nitrogen dopant, high specific surface area (SSA) and ultrathin thickness (1.5 nm), favoring catalysis and facilitating the mass transport of the reactive species. From the electrochemical tests, it is confirmed that NMCNs yield a high oxygen reduction reaction (ORR) electrocatalytic activity in acid and alkaline environment; this activity is similar or even better as compared with the one measured over carbon supported platinum commercial catalyst (40 wt % Pt/C). (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：4423 / 4431
页数：9
相关论文
共 52 条
[41]   Facile synthesis of boron and nitrogen-doped graphene as efficient electrocatalyst for the oxygen reduction reaction in alkaline media [J].
Xu, Xiao ;
Yuan, Tao ;
Zhou, Yingke ;
Li, Yawei ;
Lu, Jiming ;
Tian, Xiaohui ;
Wang, Deli ;
Wang, Jie .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (28) :16043-16052
[42]   Graphene-Based Nanosheets with a Sandwich Structure [J].
Yang, Shubin ;
Feng, Xinliang ;
Wang, Long ;
Tang, Kun ;
Maier, Joachim ;
Muellen, Klaus .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (28) :4795-4799
[43]   Strongly Veined Carbon Nanoleaves as a Highly Efficient Metal-Free Electrocatalyst [J].
Ye, Tian-Nan ;
Lv, Li-Bing ;
Li, Xin-Hao ;
Xu, Miao ;
Chen, Jie-Sheng .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (27) :6905-6909
[44]   Synthesis of 2D Nitrogen-Doped Mesoporous Carbon Catalyst for Oxygen Reduction Reaction [J].
Yu, Zhipeng ;
Piao, Jinhua ;
Liang, Zhenxing .
MATERIALS, 2017, 10 (02)
[45]   Insight into the nitrogen-doped carbon as oxygen reduction reaction catalyst: The choice of carbon/nitrogen source and active sites [J].
Zeng, Dongrong ;
Yu, Xiang ;
Zhan, Yunfeng ;
Cao, Linmin ;
Wu, Xiaoxian ;
Zhang, Bodong ;
Huang, Jilin ;
Lin, Zhipeng ;
Xie, Fangyan ;
Zhang, Weihong ;
Chen, Jian ;
Xie, Weiguang ;
Mai, Wenjie ;
Meng, Hui .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (20) :8563-8575
[46]   Polyaniline nanosheet derived B/N co-doped carbon nanosheets as efficient metal-free catalysts for oxygen reduction reaction [J].
Zhang, Yi ;
Zhuang, Xiaodong ;
Su, Yuezeng ;
Zhang, Fan ;
Feng, Xinliang .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (21) :7742-7746
[47]  
Zhao D, 1998, ADV MATER, V10, P1380, DOI 10.1002/(SICI)1521-4095(199811)10:16<1380::AID-ADMA1380>3.0.CO
[48]  
2-8
[49]   ZIF-8 Derived Graphene-Based Nitrogen-Doped Porous Carbon Sheets as Highly Efficient and Durable Oxygen Reduction Electrocatalysts [J].
Zhong, Hai-xia ;
Wang, Jun ;
Zhang, Yu-wei ;
Xu, Wei-lin ;
Xing, Wei ;
Xu, Dan ;
Zhang, Yue-fei ;
Zhang, Xin-bo .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (51) :14235-14239
[50]   Towards high-efficiency nanoelectrocatalysts for oxygen reduction through engineering advanced carbon nanomaterials [J].
Zhou, Ming ;
Wang, Hsing-Lin ;
Guo, Shaojun .
CHEMICAL SOCIETY REVIEWS, 2016, 45 (05) :1273-1307
123456