Characterization and supercapacitor application of coin-like β-nickel hydroxide nanoplates

被引:80
作者
Li, Hongliang [1 ,2 ,3 ,4 ]
Liu, Suqin [1 ,2 ]
Huang, Chenghuan [1 ,2 ,3 ,4 ]
Zhou, Zhi [1 ,2 ,3 ,4 ]
Li, Yanhua [1 ,3 ]
Fang, Dong [1 ,4 ]
机构
[1] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
[2] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
[3] Changsha Aeronaut Vocat & Tech Coll, Dept Chem Engn & Informat Engn, Changsha 410014, Hunan, Peoples R China
[4] Wuhan Text Univ, Minist Educ, Key Lab Green Proc & Funct Text New Text Mat, Wuhan 430073, Peoples R China
关键词
beta-Nickel hydroxide; Coordination homogeneous precipitation; Supercapacitor behavior; ELECTROCHEMICAL CAPACITORS; BETA-NI(OH)(2); PRECIPITATION; PERFORMANCE; BATTERIES; ENERGY; CELLS;
D O I
10.1016/j.electacta.2011.08.120
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Coin-like nickel hydroxide nanoplates are synthesized via a simple coordination homogeneous precipitation method. The structure and morphology of as-prepared products are characterized by X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy and scanning electron microscopy. It is demonstrated that the products are typical beta-nickel hydroxide with bunches coin-like nanoplates morphology. The electrochemical properties of coin-like beta-Ni(OH)(2) are examined by cyclic voltammetric, chronopotentiometry and electrochemical impedance spectroscope. Cyclic voltammetric studies show that the electrodes have good reversibility. A specific capacitance of 1532 F g(-1) is obtained at a charge/discharge current density of 0.2 A g(-1). (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:89 / 94
页数:6
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