Synthesis and crystal structure of the first Cu(I)-benzotrizolate complex [Cu4(bta)3(PPh3)4] [Cu(PPh3)3](BF4)2:: a unique tetrametallic fragment like a reverse-umbrella

被引：20
|
作者：
Li, D [1 ]
Li, RZ
Qi, ZY
Feng, XL
Cai, JW
Shi, XH
机构：
[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
[2] Zhongshan Univ, Instrumentat Anal & Res Ctr, Guangzhou 510275, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 09期
关键词：
copper(I) complex; benzotriazole; triphenylphosphine; photoluminescent;
D O I：
10.1016/S1387-7003(01)00252-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A photoluminescent polymeric Cu(I) complex containing a novel fragment [Cu-4(bta)(3)(PPh3)(4)](+) (btaH = benzotriazole) like a reverse-umbrella has been synthesized and structurally characterized. (C) 2001 Elsevier Science BN. All rights reserved.
引用
收藏
页码：483 / 485
页数：3
相关论文
共 50 条
  • [31] The crystal and electronic structure of the complex [ReCl4 (PPh3)2]
    Polyhedron, 17 (2813):
  • [32] Synthesis, crystal, molecular and electronic structure of the [ReCl4(pzH)(PPh3)] and [ReCl4(pyz)(PPh3)] complexes
    Machura, B
    Jankowska, A
    Kruszynski, R
    Klak, J
    Mrozinski, J
    POLYHEDRON, 2006, 25 (06) : 1348 - 1358
  • [33] Synthesis and structure of [nPr3N(CH2)6NnPr3][CuFe3Br3(SePh)6], [Cu5Fe(SePh)7(PPh3)4] and [Cu4Fe3(SePh)10(PPh3)4]
    Eichhoefer, Andreas
    Fenske, Dieter
    Olkowska-Oetzel, Jolanta
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (01) : 74 - 79
  • [34] 五配位Cu（Ⅰ）配合物[Cu（4′-Phtpy）(PPh3)2]（BF4）的合成、结构及光谱性质研究
    冯巧
    李丹
    尹业高
    冯小龙
    蔡继文
    化学学报, 2002, (12) : 2167 - 2171
  • [35] Thiolate-bridged polynuclear clusters of copper(I) and silver(I): Syntheses and structures of [Cu8(μ4-SPh)6(PPh3)4(MeCN)4][(CdI)3Cu(μ-SPh)6], [Cu8(μ-SPh)4(μ3-SPh)4(PPh3)4], [Cu14(μ6-S)(μ3-SPhMe-4)12(PPh3)6], and [Ag14(μ6-Br)(μ3-SPh)12(PPh3)8]Cl
    Xu, Chao
    Yi, Xiao-Yi
    Duan, Tai-Ke
    Chen, Qun
    Zhang, Qian-Feng
    POLYHEDRON, 2011, 30 (16) : 2637 - 2643
  • [36] STRUCTURAL COMPARISON OF CLUSTER COMPOUNDS CONTAINING AN EDGE-BRIDGING CU(PPH3), AG(PPH3), AU(PPH3) FRAGMENT - X-RAY CRYSTAL-STRUCTURE OF [AGRU3(CO)9(C2BUT)(PPH3)]
    ADATIA, T
    MCPARTLIN, M
    SALTER, ID
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (11): : 2889 - 2891
  • [37] SELF ASSEMBLY OF ISOSTRUCTURAL COPPER(I)-SILVER(I) BUTTERFLY CLUSTERS WITH 2-MERCAPTOTHIAZOLINE - SYNTHESES AND STRUCTURES OF (PPH3)2CU4(C3H4NS2)4, [(C5H5N)CU4(C3H4NS2)4]N, (PPH3)2AG4(C3H4NS2)4 AND (PPH3)2AG2CU2(C3H4NS2)4
    FACKLER, JP
    LOPEZ, CA
    STAPLES, RJ
    WANG, SN
    WINPENNY, REP
    LATTIMER, RP
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (02) : 146 - 148
  • [38] STERIC EFFECTS AND THE BEHAVIOR OF CU(NN)(PPH3)2+ SYSTEMS IN FLUID SOLUTION - CRYSTAL AND MOLECULAR-STRUCTURES OF [CU(DMP)(PPH3)2]NO3 AND [CU(PHEN)(PPH3)2]NO3.11/2ETOH
    KIRCHHOFF, JR
    MCMILLIN, DR
    ROBINSON, WR
    POWELL, DR
    MCKENZIE, AT
    CHEN, S
    INORGANIC CHEMISTRY, 1985, 24 (23) : 3928 - 3933
  • [39] Synthesis and crystal structure of [NEt4][CoCl3(PPh3)]
    Li, GQ
    Zheng, FK
    Guo, GC
    Huang, JS
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (03) : 230 - 233
  • [40] Growth of sphere- and tetrapod-shaped Cd(Cu)Se nanocrystals from Cu(C17H35COO)2 and Cu4(PPh3)4(μ3-I)4
    Tananaev, Peter N.
    Dorofeev, Sergey G.
    Vasiliev, Roman B.
    Znamenkov, Konstantin O.
    Kuznetsova, Tatyana A.
    MENDELEEV COMMUNICATIONS, 2009, 19 (03) : 131 - 132
12345