Synthesis and crystal structure of the first Cu(I)-benzotrizolate complex [Cu4(bta)3(PPh3)4] [Cu(PPh3)3](BF4)2:: a unique tetrametallic fragment like a reverse-umbrella

被引:20
|
作者
Li, D [1 ]
Li, RZ
Qi, ZY
Feng, XL
Cai, JW
Shi, XH
机构
[1] Shantou Univ, Dept Chem, Shantou 515063, Guangdong, Peoples R China
[2] Zhongshan Univ, Instrumentat Anal & Res Ctr, Guangzhou 510275, Peoples R China
关键词
copper(I) complex; benzotriazole; triphenylphosphine; photoluminescent;
D O I
10.1016/S1387-7003(01)00252-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A photoluminescent polymeric Cu(I) complex containing a novel fragment [Cu-4(bta)(3)(PPh3)(4)](+) (btaH = benzotriazole) like a reverse-umbrella has been synthesized and structurally characterized. (C) 2001 Elsevier Science BN. All rights reserved.
引用
收藏
页码:483 / 485
页数:3
相关论文
共 50 条
  • [1] Synthesis and crystal structure of [Cu(HIm)2(PPh3)2] (BF4)
    Li, D
    Li, RZ
    Qi, ZY
    Xu, YP
    Feng, XL
    Cai, JW
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2001, 17 (04) : 593 - 596
  • [2] Synthesis, structure and spectroanalysis studies of a five-coordinated Cu(I) complex [Cu(4′-Phtpy)(PPh3)2](BF4)
    Feng, Q
    Li, D
    Yin, YG
    Feng, XL
    Cai, JW
    ACTA CHIMICA SINICA, 2002, 60 (12) : 2167 - 2171
  • [3] Synthesis and structure of the copper( I ) complex [Cu(PPh3)2(BH4)]
    Li, CY
    Zhang, YG
    Zhou, Y
    Zhang, LF
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (02) : 91 - 94
  • [4] Synthesis and Structure of the Copper(Ⅰ) Complex 〔Cu(PPh3)2(BH4)〕
    LI Cai Yun ZHANG Ying Gui ZHOU Yong (Chemistry Department of Pingyuan University
    结构化学, 2000, (02) : 91 - 94
  • [5] Four novel mononuclear and polynuclear Cu(I) thiosaccharinates with triphenylphosphane and bis(diphenylposphino)methane. Synthesis and structural study of Cu4(tsac)4(PPh3)3, Cu(tsac)(PPh3)2, Cu4(tsac)4(dppm)2, and Cu2(tsac)2(dppm)2
    Dennehy, Mariana
    Telleria, Gabriela P.
    Quinzani, Oscar V.
    Echeverria, Gustavo A.
    Piro, Oscar E.
    Castellano, Eduardo E.
    INORGANICA CHIMICA ACTA, 2009, 362 (08) : 2900 - 2908
  • [6] Crystal and molecular structure of copper( I ) complex [Cu(PPh3)2(NO3)]
    Yang, RN
    Li, TX
    Sun, YA
    Hu, XY
    Jin, DM
    Luo, BS
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (02) : 126 - 130
  • [7] Crystal and Molecular Structure of Copper(Ⅰ) Complex 〔Cu(PPh3)2(NO3)〕
    YANG Rui Na * LI Tian Xian SUN Yu An 1 HU Xiao Yuan JIN Dou Man LUO Bao Sheng 2 (Henan Institute of Chemistry
    结构化学, 2000, (02) : 126 - 130
  • [8] Synthesis, structures and theoretical investigation of [Cu4(P2S6)(PPh3)4], [Cu6(P2S6)Cl2(PPh3)6], and [Au4(P2S6)(PPh3)4]
    Weigend, F
    Wirth, S
    Ahlrichs, R
    Fenske, D
    CHEMISTRY-A EUROPEAN JOURNAL, 2000, 6 (03) : 545 - 551
  • [9] [Cu(HIm)2(PPh3)2](BF4)的合成与晶体结构
    李丹
    李蓉珍
    齐志宇
    徐严平
    冯小龙
    蔡继文
    无机化学学报, 2001, (04) : 593 - 596
  • [10] Syntheses, crystal structures and photoluminescence of [Au2(PPh3)2(μ-4,4′-bpy)](ClO4)2 and [Cu2(PPh3)4(CH3CN)2(μ-4,4′-bpy)](BF4)2 complexes
    Li, D
    Qi, ZY
    Feng, Q
    Li, RZ
    Feng, XL
    Cai, JW
    ACTA CHIMICA SINICA, 2002, 60 (09) : 1637 - 1643