Studies on the dielectric properties of poly(o-toluidine) and poly(o-toluidine-aniline) copolymer

被引:12
|
作者
John, H
Thomas, RM
Mathew, KT
Joseph, R [1 ]
机构
[1] Cochin Univ Sci & Technol, Dept Polymer Sci & Rubber Technol, Cochin 682022, Kerala, India
[2] Cochin Univ Sci & Technol, Dept Elect, Cochin 682022, Kerala, India
关键词
polyaniline; poly(o-toluidine); conductivity; frequency; poly(o-toluidine co aniline);
D O I
10.1002/app.20044
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(o-toluidine) (PoT) and poly(o-toluidine co aniline) were prepared by using ammonium persulfate initiator, in the presence of 1M HCl. It was dried under different conditions: room temperature drying (48 h), oven drying (at 50degreesC for 12 h), or vacuum drying (under vacuum, at room temperature for 16 h). The dielectric properties, such as dielectric loss, conductivity, dielectric constant, dielectric heating coefficient, loss tangent, etc., were studied at micro-wave frequencies. A cavity perturbation technique was used for the study. The dielectric properties were found to be related to the frequency and drying conditions. Also, the copolymer showed better properties compared to PoT alone. (C) 2004 Wiley Periodicals, Inc.
引用
收藏
页码:592 / 598
页数:7
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