Control of intramolecular orbital alignment in the photodissociation of thiophenol: Conformational manipulation by chemical substitution

被引：58
作者：
Lim, Jeong Sik [1 ,2 ]
Lee, Yoon Sup [1 ,2 ]
Kim, Sang Kyu [1 ,2 ]
机构：
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Sch Mol Sci BK21, Taejon 305701, South Korea
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 10期
关键词：
conformational isomerism; conical intersections; photodissociation; reaction mechanisms;
D O I：
10.1002/anie.200705358
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Graph Presented) Intramolecular orbital alignment can be controlled by conformational tuning of the initial wavepacket location on the two-dimensional potential-energy surfaces of thiophenol (see picture; CI = conical intersection). Chemical substitution induces conformational preference, leading to a dramatic change of the branching ratio between X̃ and à states of the phenylthiyl radical. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1853 / 1856
页数：4
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