Applying the Oligomer Approach to Luminescent Conjugated Organoboranes

被引：73

作者：

Chen, Pangkuan ^{[1
]}

Lalancette, Roger A. ^{[1
]}

Jaekle, Frieder ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 23期

基金：

美国国家科学基金会;

关键词：

ELECTRONIC DELOCALIZATION; PI-CONJUGATION; POLYMERS; BORON; MONODISPERSE; PHENYLENE; DESIGN; LENGTH; POLYFLUORENES; POLYTHIOPHENE;

D O I：

10.1021/ja201436a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of highly luminescent monodisperse fluoreneborane oligomers (n = 1-6) were prepared using a new iterative synthetic procedure that takes advantage of the highly selective and differential reactivity of bromoboranes with arylsilanes and arylstannanes. Cyclic and square wave voltammetry revealed a gradual decrease of the LUMO energy levels with increasing chain length, while absorption and emission data showed a bathochromic shift and increase in quantum efficiency. An extended conjugation length of n(ECL) = S was derived.

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页码：8802 / 8805

页数：4

相关论文

共 65 条

[1] Electropolymerizable 2,2'-Carboranyldithiophenes. Structure-Property Investigations of the Corresponding Conducting Polymer Films by Electrochemistry, UV-Visible Spectroscopy and Conducting Probe Atomic Force Microscopy [J].

Barriere, Frederic ;

Fabre, Bruno ;

Hao, Erhong ;

LeJeune, Zorabel M. ;

Hwang, Euiyong ;

Garno, Jayne C. ;

Nesterov, Evgueni E. ;

Vicente, M. Graca H. .

MACROMOLECULES, 2009, 42 (08) :2981-2987

[2] Organophosphorus π-conjugated materials [J].

Baumgartner, Thomas ;

Reau, Regis .

CHEMICAL REVIEWS, 2006, 106 (11) :4681-4727

[3] Polyfluorenes with on-chain dibenzoborole units -: Synthesis and anion-induced photoluminescence quenching [J].

Bonifacio, Vasco D. B. ;

Morgado, Jorge ;

Scherf, Ullrich .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (08) :2878-2883

[4]

Brook MA., 2000, SILICON ORGANIC ORGA

[5] Borole/thiophene cooligomers and copolymers with quinoid structures and biradical characters [J].

Cao, H ;

Ma, J ;

Zhang, GL ;

Jiang, YS .

MACROMOLECULES, 2005, 38 (04) :1123-1130

[6] Synthesis of Functionalizable Boron-Containing π-Electron Materials that Incorporate Formally Aromatic Fused Borepin Rings [J].

Caruso, Anthony, Jr. ;

Siegler, Maxime A. ;

Tovar, John D. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (25) :4213-4217

[7] Organoboron Polymers for Photovoltaic Bulk Heterojunctions [J].

Cataldo, Sebastiano ;

Fabiano, Simone ;

Ferrante, Francesco ;

Previti, Francesco ;

Patane, Salvatore ;

Pignataro, Bruno .

MACROMOLECULAR RAPID COMMUNICATIONS, 2010, 31 (14) :1281-1286

[8] Synthesis and electrochemical properties of a new class of boron-containing n-type conjugated polymers [J].

Chai, Jianfang ;

Wang, Chao ;

Jia, Li ;

Pang, Yi ;

Graham, Matthew ;

Cheng, Stephen Z. D. .

SYNTHETIC METALS, 2009, 159 (14) :1443-1449

[9] Synthesis and Properties of Carborane-Appended C3-Symmetrical Extended π Systems [J].

Dash, Barada Prasanna ;

Satapathy, Rashmirekha ;

Gaillard, Elizabeth R. ;

Maguire, John A. ;

Hosmane, Narayan S. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (18) :6578-6587

[10] Synthesis and energy-transfer properties of hydrogen-bonded oligofluorenes [J].

Dudek, SP ;

Pouderoijen, M ;

Abbel, R ;

Schenning, APHJ ;

Meijer, EW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (33) :11763-11768

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