Complete oxidation of formaldehyde at ambient temperature over supported Pt/Fe2O3 catalysts prepared by colloid-deposition method

被引：179
作者：
An, Nihong [1 ]
Yu, Qiushi [1 ]
Liu, Gang [1 ]
Li, Suying [1 ]
Jia, Mingjun [1 ]
Zhang, Wenxiang [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Theoret & Computat Chem, Changchun 130023, Peoples R China
来源：
JOURNAL OF HAZARDOUS MATERIALS | 2011年 / 186卷 / 2-3期
基金：
美国国家科学基金会;
关键词：
Platinum catalysts; Colloid deposition; Formaldehyde; Complete oxidation; MANGANESE-PALLADIUM; OXIDE CATALYSTS; METAL-CATALYSTS; CO OXIDATION; PLATINUM; PERFORMANCE; METHANOL; COMBUSTION; MECHANISM; CARBON;
D O I：
10.1016/j.jhazmat.2010.12.018
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The catalytic properties of iron oxide supported platinum catalysts (Pt/Fe2O3), prepared by a colloid deposition route, were investigated for the complete oxidation of formaldehyde. It is found that all the Pt/Fe2O3 catalysts calcined at different temperatures (200-500 degrees C) were active for the oxidation of formaldehyde. Among them, the catalysts calcined at lower temperatures (i.e., 200 and 300 degrees C) exhibited relatively high catalytic activity and stability, which could completely oxidize HCHO even at room temperature. Based on a variety of physical-chemical characterization results, it is proposed that the presence of suitable interaction between Pt particles and iron oxide supports, which is mainly in the form of Pt-O-Fe bonds, should play a positive role in determining the catalytic activity and stability of the supported Pt/Fe2O3 catalysts. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：1392 / 1397
页数：6
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