Room-Temperature Synthesis of Covalent Organic Framework (COF-LZU1) Nanobars in CO2/Water Solvent

被引：57

作者：

Zhang, Fanyu ^{[1
,2
]}

Zhang, Jianling ^{[1
,2
]}

Zhang, Bingxing ^{[1
,2
]}

Tan, Xiuniang ^{[1
,2
]}

Shao, Dan ^{[1
,2
]}

Shi, Jinbiao ^{[1
]}

Tan, Dongxing ^{[1
,2
]}

Liu, Lifei ^{[1
,2
]}

Feng, Jiaqi ^{[3
]}

Han, Buxing ^{[1
,2
]}

Yang, Guanying ^{[1
,2
]}

Zheng, Lirong ^{[4
]}

Zhang, Jing ^{[4
]}

机构：

[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Sch Chem & Chem Engn, Beijing 100049, Peoples R China

[3] Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China

[4] Chinese Acad Sci, Inst High Energy Phys, Beijng Synchrotron Radiat Facil, Beijing 100049, Peoples R China

来源：

CHEMSUSCHEM | 2018年 / 11卷 / 20期

基金：

中国国家自然科学基金;

关键词：

carbon dioxide; heterogeneous catalysis; covalent organic frameworks; nanostructures; HETEROGENEOUS CATALYSTS; CARBON-DIOXIDE; CO2; CRYSTALLINE; GENERATION; REDUCTION; POLYMERS; HYDROGEN; LIQUIDS; METHANE;

D O I：

10.1002/cssc.201801712

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The development of facile, rapid, low-energy, environmentally benign routes for the synthesis of covalent organic frameworks (COFs) is of great interest. This study concerns the utilization of water containing dissolved CO2 as a solvent for the room-temperature synthesis of COF. The as-synthesized particles, denoted COF-LZU1, combine advantages of good crystallinity, nanoscale size, and high surface area, which suggests promising application as a support for heterogeneous catalysts. Moreover, this versatile CO2-assisted method is also applicable for the room-temperature synthesis of Cu-COF-LZU1. This method gives rise to new opportunities for fabricating COFs and COF-based materials with different compositions and structures.

引用

页码：3576 / 3580

页数：5

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