Growth and characterization of cobalt thiourea sulfate, a new nonlinear optical material

被引：15
|
作者：
Kirubavathi, K.
Selvaraju, K.
Valluvan, R.
Kumararaman, S. [1 ]
机构：
[1] Nehru Mem Coll, Dept Phys, Puthanampatti 621007, Tamil Nadu, India
[2] Thanthai Hans Roever Coll, Dept Phys, Perambalur 621212, India
来源：
MATERIALS LETTERS | 2007年 / 61卷 / 19-20期
关键词：
solution growth technique; X-ray diffraction; NLO property;
D O I：
10.1016/j.matlet.2007.01.082
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new semi-organic nonlinear optical crystal of cobalt thiourea sulfate (CTS) has been grown by solvent evaporation solution growth method at room temperature. The unit cell parameters were evaluated by single crystal X-ray diffraction technique. The vibrational frequencies of various functional groups in the crystals have been derived from FT-IR analysis. The range and percentage of optical transmission are ascertained by recording the UV-VIS-NIR spectrum. The thermal behavior of the crystals has been investigated by DTA and TGA analyses. The mechanical property of the grown crystals has been analyzed by Vicker's microhardness method. The NLO property of the grown crystal has been confirmed by the Kurtz powder second harmonic generation (SHG) test. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：4173 / 4176
页数：4
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