Magnetic and Conductive Ni/Carbon Aerogels toward High-Performance Microwave Absorption

被引:58
作者
Zhao, Hai-Bo [1 ]
Fu, Zhi-Bing [2 ]
Liu, Xue-Yi [3 ]
Zhou, Xiao-Cao [2 ]
Chen, Hong-Bing [4 ]
Zhong, Ming-Long [2 ]
Wang, Chao-Yang [2 ]
机构
[1] Sichuan Univ, Natl Engn Lab Ecofriendly Polymer Mat Sichuan, Coll Chem, Ctr Degradable & Flame Retardant Polymer Mat, Chengdu 610064, Sichuan, Peoples R China
[2] China Acad Engn Phys, Res Ctr Laser Fus, Mianyang 621000, Sichuan, Peoples R China
[3] Henan Normal Univ, Affiliated Middle Sch, Xinxiang 453000, Henan, Peoples R China
[4] China Acad Engn Phys, Inst Nucl Phys & Chem, Mianyang 621000, Sichuan, Peoples R China
基金
中国国家自然科学基金;
关键词
EXCELLENT ELECTROMAGNETIC ABSORPTION; FACILE SYNTHESIS; ELEVATED-TEMPERATURE; ABSORBING MATERIAL; WAVE ABSORPTION; CARBON NANOTUBE; GRAPHENE FOAM; ULTRALIGHT; MICROSPHERES; COMPOSITES;
D O I
10.1021/acs.iecr.7b03612
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Novel magnetic and conductive Ni/carbon aerogels have been successfully fabricated through an autocatalytic reduction process. The resultant Ni/carbon aerogels have nanoporous structure with high specific surface area, low densities, appropriate electrical conductivities and controllable magnetization. Due to these special attributes, the aerogel composites are demonstrated to be a great microwave absorbent possessing strong and controllable EM absorption with ultrathin thickness. Only with filler loading of 10 wt % in the wax, a minimum RL of -57 dB is found at 13.3 GHz with the thickness of 2 mm. Even with the thickness of 1.5 mm, the Ni/carbon aeroge1-3 composite can exhibit the low RLmin value of -32 dB and wide effective EM absorption bandwidth of 4.0 dB. The synergistic effect of the medium dielectric loss, weak magnetic loss and good impedance match, accounts for the high microwave absorption performance.
引用
收藏
页码:202 / 211
页数:10
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